2591-44-8

Usage

Uses

Used in Household Insect Sterilization Products:
(2-Methylallyl)triphenylstannane is used as an insect reproduction inhibitor for controlling the population of insects in household settings. The triphenylstannane component of the compound exhibits promising properties for the reproduction control of insects and related species from several orders of arthropods, making it an effective agent in managing insect infestations.

Upstream product

• 3017-69-4 2-methyl-1-propenylbromide 
• 639-58-7 triphenyltin chloride 
• 1458-98-6 2-methyl-3-bromo-1-propene 
• 33324-92-4 (2-methylallyl)magnesium bromide 
• 67883-62-9 2-methylallyltributyltin 
• 76-63-1 allytriphenyltin 

Downstream Products

• 134311-01-6 2-methyl-4,4-bis(p-methoxyphenyl)-1-butene 
• 16192-04-4 1-methyl-4-(2-methylallylsulfonyl)benzene 
• 1206-41-3 N-(2-methylallyl)-4-toluenesulfonamide 
• 70-55-3 toluene-4-sulfonamide 
• 10347-39-4 ((C₆H₅)3Sn)2S₃ 
• 595-90-4 tetraphenyltin(IV) 
• 115205-84-0 (4S,5S)-4-isobutenyl-3,5-dibenzyloxazolidin-2-one 
• 115205-85-1 (4R,5R)-4-isobutenyl-3,5-dibenzyloxazolidin-2-one 
• 78249-22-6 (-)-(4S,5S)-2-<(2S,3S,4R,5S)-7-(Benzyloxy)-3,5-(benzylidenedioxy)-4-methoxy-2-(2-methylprop-2-enyl)heptyl>-4-(methoxymethyl)-5-phenyl-2-oxazoline 
• 78306-80-6 (4R,5S)-5-((1S,2R)-4-Benzyloxy-2-hydroxy-1-methoxy-butyl)-4-(2-methyl-allyl)-dihydro-furan-2-one 
• 78249-15-7 (+)-(4S,5S)-4-(2-Methyl-2-propenyl)-5-<(1S,2R)-4-(benzyloxy)-2-hydroxy-1-methoxybutyl>dihydrofuran-2(3H)-one 

Relevant academic research and scientific papers

Wurtz-type reductive coupling reaction of allyl bromides and haloorganotins in cosolvent/H2O(NH4Cl)/Zn media as a route to allylstannanes and hexaaryldistannanes

Twenty-one allylstannanes have been prepared via a simple Wurtz-type coupling reaction of allyl bromides and R3SnX compounds (R = Me, Et, Pr, Bu, Ph; X = Cl, I, OH), Bu2SnCl2, and (Bu2SnCl)2O in cosolvent/H2O (NH4Cl saturated) media under the mediation of zinc powder. Also R3SnSnR3 compounds (R = Ph, p- and m-Tol) have been prepared via coupling of triaryltin chlorides. The stereochemical course of the reaction between R3SnCl and (C4H7)Br (C4H7 = α-methylallyl, trans- and cis-crotyl) has been extensively studied. Two distinct reactions are involved in the overall process: (i) the coupling reaction, which gives rise stereoselectively to the sole R3SnCH(CH3)CH=CH2 (α-isomer), and (ii) the subsequent isomerization of the α-isomer furnishing mixtures of (α, trans, cis)-isomers. The occurrence of reaction ii depends upon the nature either of the R group or the employed cosolvent. In cyclohexane, the α-isomer is exclusively obtained with R = Bu, while with R = Me, Et, and Pr it is found as a major component in the ternary isomeric mixture. In tetrahydrofuran, 2-propanol, acetonitrile, and pyridine, the isomerization occurs to an extent which depends on the polarity and the coordinating ability of the cosolvent itself. The observed stereoselection has been hypothesized to occur through one-electron transfer from the zinc metal to the (C4H7)Br to form stereoselectively an adsorbed CH2=CHCH(CH3)Br?-Zn?+ radical ion which is trapped by the R3SnCl reactant to form the α-isomer. Similarly, ditin compounds are thought to be formed by interaction of R3SnCl?-Zn?+ radical ions with R3SnCl molecules.

Metal-ion-catalyzed Fluxionality of Pentadienyltins and Its Application to the Diels-Alder Reaction

(Z)-Pentadienyltins (PDT) as well as (Z)-allylic tins are isomerized to (E)-isomers most effectively by alkaline earth metal ions.The resulted (E)-PDT is trapped by 1,4-naphthoquinone to give the Diels-Alder adducts efficiently behaving as a reactive equivalent of 1,3-pentadiene.