259250-91-4Relevant academic research and scientific papers
A novel approach to bicyclic fused cyclopentenone derivatives
Deng, Guisheng,Tian, Xue,Wang, Jianbo
, p. 587 - 589 (2007/10/03)
A new four-step reaction sequence leading to bicyclic fused cyclopentenone derivatives starting from cyclic ketones has been developed.
A short protocol for the synthesis of spirocyclic tetrahydrofurans via intramolecular O-H insertion
Jones, Keith,Toutounji, Teymour
, p. 2427 - 2431 (2007/10/03)
The conversion of cyclic ketones to functionalised spirocyclic tetrahydrofurans via a three-step sequence of acetoacetate ester dianion-aldol reaction, diazo-transfer and carbene O-H insertion is described.
Rhodium(II)- and copper(I)-catalyzed intramolecular carbon-hydrogen bond insertions with metal carbenoids derived from diazo ketones
Mueller, Paul,Maitrejean, Esther
, p. 1807 - 1826 (2007/10/03)
The decomposition of diazo ketones in the presence of Rh(II) and Cu(I) catalysts affords products of C-H bond insertion in high yields. The effect of structural variation on intramolecular and transannular C-H insertions of diazo ketones has been investig
