2595-41-7Relevant academic research and scientific papers
S -Glycosides: Synthesis of S -linked arabinoxylan oligosaccharides
Boos, Irene,Clausen, Mads H.,Jiang, Hao,Romanò, Cecilia
supporting information, p. 2696 - 2701 (2020/04/17)
S-Glycosides are important tools for the elucidation of specific protein-carbohydrate interactions and can significantly aid structural and functional studies of carbohydrate-active enzymes, as they are often inert or act as enzyme inhibitors. In this con
Synthesis of novel thioglycoside derivatives containing quinazolinone
Huang, Hui,Gao, Jian-Fang,Cao, Ling-Hua,Wang, Duo-Zhi,Zhang, Jian-Bin,Zhou, Shu-Bao,Zhou, Yu-Qiang
scheme or table, p. 419 - 424 (2009/12/06)
Aseries of novel thioglycoside derivatives containing 4(3H)-quinazolinone was designed and synthesized from 2-chloromethyl-quinazolin-4(3H)-ones and 1-thioglycose. Several 2-chloromethyl-quinazolin-4(3H)-ones were synthesized on refluxing with 2-(chloroacetylamino)-benzoic acid and arylamines in acetonitrile. All of the novel compounds were characterized by IR, 1H NMR spectra and elemental analysis. The structures of compounds 7b, 8b and 8c have been determined by X-ray diffraction analysis.
Stereoselective synthesis of thioxylooligosaccharides from S-glycosyl isothiourea precursors
Ibatullin, Farid M,Shabalin, Konstantin A.,J?nis, Janne V.,Selivanov, Stanislav I.
, p. 4565 - 4567 (2007/10/03)
A stereoselective synthesis of thioxylo-di-, -tri-, -tetra- and -penta-saccharides from S-glycosyl isothiourea precursors is described. The synthesis was performed starting from 2,3,4-tri-O-acetyl-β-D-xylopyranosyl isothiouronium bromide using a triethylamine promoted reaction with 1,2,3-tri-O-benzoyl-4-O-trifluoromethanesulphonyl-β-L-arabinopyranose. The resulting 4-thioxylobiose was then converted into the corresponding isothiouronium bromide and used for the synthesis of 4,4′-dithioxylotriose. Higher homologues of the series and their α-methyl glycosides were also prepared.
