259546-65-1Relevant articles and documents
Efficient method for the one-pot azidation of alcohols using bis(p-nitrophenyl) phosphorazidate
Mizuno, Masanori,Shioiri, Takayuki
, p. 2165 - 2166 (1997)
The direct stereoselective conversion of various alcohols and hexopyranoses into the corresponding alkyl azides and glycosyl azides, respectively, is efficiently accomplished by using bis(p-nitrophenyl) phosphorazidate and DBU.
Gold-catalysed glycosylation reaction using an easily accessible leaving group
Koppolu, Srinivasa Rao,Niddana, Ramana,Balamurugan, Rengarajan
, p. 5094 - 5097 (2015/05/13)
Gold(iii)-catalysed glycosylation reaction has been developed by employing a new and easily accessible leaving group synthesized from ethyl cyanoacetate. Several nucleophiles like alcohols, thiols, allyltrimethylsilane, trimethylsilyl azide and triethylsilane have been reacted to make the corresponding glycosides in good yields and with marginal to excellent α-selectivity. This journal is