259753-76-9Relevant academic research and scientific papers
Experimental and theoretical studies on circularly polarized phosphorescence of a [2.2]paracyclophane-based platinum(ii) complex
Inoue, Ryo,Kondo, Riki,Morisaki, Yasuhiro
, p. 15438 - 15441 (2020)
An optically active binuclear platinum(ii) complex based on planar chiral [2.2]paracyclophane was synthesized. The corresponding enantiomers exhibited red circularly polarized phosphorescence (CPP) with the dissymmetry factor |glum| = 1.0 × 10-3. We report, for the first time, theoretical estimation of the CPP |glum| value using relativistic calculations.
