259877-35-5Relevant academic research and scientific papers
The stereoselective total synthesis of PF1163A
Kumar, Harish,Reddy, A. Srinivas,Reddy, B.V. Subba
, p. 1519 - 1522 (2014/03/21)
A stereoselective total synthesis of 13-membered macrocycle PF1163A, an antifungal agent, has been accomplished for the first time starting from d-xylose. This approach involves a diastereoselective allylation of lactal ether,3a reductive ring
Highly diastereoselective allylation of lactols and their ethers using molecular iodine
Yadav,Reddy, B.V. Subba,Reddy, A. Srinivas,Reddy, Ch. Suresh,Raju, S. Satyanarayana
scheme or table, p. 6631 - 6634 (2010/03/01)
Lactols and their ethers undergo smooth allylation with allyltrimethylsilane in the presence of 5 mol % iodine in dichloromethane at -78 °C to afford C-allylfuranosides in good yields and with high diastereoselectivity. The use of iodine makes this method
