25992-30-7

Basic information

• Product Name: 2-methyl-5-(2-methyl-3-methylidenebicyclo[2.2.1]hept-2-yl)pentan-1-ol
• Synonyms: 2-(4-Hydroxymethylpentyl)-2-methyl-3-methylenebicyclo(2.2.1)heptane; 2-Methyl-5-(2-methyl-3-methylenebicyclo[2.2.1]hept-2-yl)pentan-1-ol; Bicyclo(2.2.1)heptane-2-pentanol, beta,2-dimethyl-3-methylene-; bicyclo[2.2.1]heptane-2-pentanol, beta,2-dimethyl-3-methylene-
• CAS NO: 25992-30-7
• Molecular Formula: C₁₅H₂₆O
• Molecular Weight: 222.3663
• Mol File: 25992-30-7.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 304.6°C at 760 mmHg
• Flash Point: 110.3°C
• Density: 0.95g/cm³
• Vapor Pressure: 8.23E-05mmHg at 25°C
• Refractive Index: 1.498
• CAS DataBase Reference: 2-methyl-5-(2-methyl-3-methylidenebicyclo[2.2.1]hept-2-yl)pentan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-5-(2-methyl-3-methylidenebicyclo[2.2.1]hept-2-yl)pentan-1-ol(25992-30-7)
• EPA Substance Registry System: 2-methyl-5-(2-methyl-3-methylidenebicyclo[2.2.1]hept-2-yl)pentan-1-ol(25992-30-7)

Safety Data

• Hazardous Substances Data: 25992-30-7(Hazardous Substances Data)

Upstream product

• 73838-28-5 ethyl 3-(anti-1,7-dimethyl-2-(acetylamino)bicyclo<2.2.1>hept-7-yl)propanoate 
• 69667-88-5 ethyl 3-(2-exo-methyl-3-methylenebicyclo<2.2.1>hept-2-yl)propanoate 
• 73838-31-0 3-(2exo-methyl-3-methylidene-bicyclo<2.2.1>hept-2-yl)propanal 
• 27548-52-3 (E/Z)-ethyl 2-methyl-5-(2exo-methyl-3-methylidene-bicyclo<2.2.1>hept-2-yl)-2-pentenoate 

Relevant articles and documents

East Indian Sandalwood Oil. 2. Stereoselective Synthesis of (+/-)-Epi-β-santalene and (+/-)-Epi-β-santalol

Acid-catalyzed rearrangement of γ-lactone 6 in the presence of acetonitrile provides a mixture of amide acids, which are readily separated as their ethyl esters 18-20.The major product 18, when subjected to fragmentation, provides esters 21 and 22 (92percent and 8percent, respectively).The structure of 21 has been confirmed by its conversion, via aldehyde 23, to (+/-)-epi-β-santalene (8).Similarly, the structure of 22 has been confirmed by its conversion to (+/-)-α-santalene (3). (+/-)-Epi-cis-β-santalol (9), (+/-)-epi-trans-β-santalol (10), and (+/-)-dihydroepi-β-santalol (11) have also been prepared via aldehyd 23.