260265-77-8Relevant articles and documents
Selective synthesis and kinetic measurement of 1:1 and 2:2 cyclic compounds containing 1,4,7,10-tetraazacyclododecane and azobenzene units
Wei,Tomohiro,Kodaka,Okuno
, p. 8979 - 8987 (2007/10/03)
1:1 cyclic compounds 8a-c (51-55%) and 2:2 cyclic compounds 9a-c (20-49%) containing 1,4,7,-10-tetraazacyclododecane (cyclen) and azobenzene units were selectively synthesized under UV irradiation (330 nm ?, ΔH?, and ΔS?) of 8a-c and 9a-c were studied in nonpolar media (benzene) and polar media (methanol). The cis to trans isomerization rates in the dark for these cyclic compounds increase with ring size or structural flexibility (8a ? dominates ΔG? in cyclic compounds.