26031-70-9

Basic information

• Product Name: 2-(1-pyridinium)-1-(2'-nitrophenyl)ethanone bromide
• Synonyms: 2-(1-pyridinium)-1-(2'-nitrophenyl)ethanone bromide
• CAS NO: 26031-70-9
• Molecular Weight: 323.146
• Mol File: 26031-70-9.mol

Chemical Properties

• CAS DataBase Reference: 2-(1-pyridinium)-1-(2'-nitrophenyl)ethanone bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1-pyridinium)-1-(2'-nitrophenyl)ethanone bromide(26031-70-9)
• EPA Substance Registry System: 2-(1-pyridinium)-1-(2'-nitrophenyl)ethanone bromide(26031-70-9)

Safety Data

• Hazardous Substances Data: 26031-70-9(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 6851-99-6 2-bromo-1-(2-nitrophenyl)ethanone 
• 577-59-3 2-acetylnitrobenzene 

Downstream Products

• 52089-83-5 1-(2-hydroxy-2'-nitrophenylethyl)pyridinium bromide 

Relevant articles and documents

Synthesis and Nitration of Some Thieno-fused Analogues of the Benzo[a]quinolizinium Cation

Three thieno-fused analogues of benzo[a]quinolizinium (1), thieno[3,2-a]- and thieno[2,3-a]quinolizinimn 4 and 5 and thiazolo[2,3-a]isoquinolinium (6), were synthesized by photocyclization of 1-(2-thienylvinyl)pyridinium salts 9a and 9b and 3-styrylthiazolium salt 9c, respectively. The nitration of the compounds 4, 5, and 6 occurred predominantly at positions 2, 3, and 7, respectively, while the nitro group was introduced into the 8- and 10-positions of 1 in the ratio of 68:32. The nmr and uv spectral properties and reduction potentials of 4-6 were also compared with those of the parent compound 1.

Base-mediated 1,3-dipolar cycloaddition of pyridinium bromides with bromoallyl sulfones: a facile access to indolizine scaffolds

An expedient and transition-metal-free synthetic strategy has been developed for the construction of substituted indolizines from a unique combination of pyridinium salts and 2-bromoallyl sulfones. This approach does not compromise with the diverse substitutions on both the pyridinium salts and 2-bromoallyl sulfones. Wide substrate scope, operational simplicity, milder reaction conditions and good to moderate yields are the merits associated with the current approach. Moreover, this method provides two products which are amenable for the generation of a library of key indolizine building blocks. This journal is

Facile one-pot tandem synthesis of perfluoroalkylated indolizines under metal-free mild conditions

A direct metal-free method for the synthesis of perfluoroalkylated indolizines by means of DIPEA-promoted tandem C[sbnd]N/C[sbnd]C bond formation was developed. Various substituted pyridines and bromoacetyl derivatives with methyl perfluoroalk-2-ynoates proceeded smoothly in this mild transformation, and the desired products were obtained in good to excellent yields under air.