260371-27-5

Basic information

• Product Name: Pd(C₆H₅CC)(C₆H₅)2PC₆H₄CHNNC(O)C₆H₄NO₂
• CAS NO: 260371-27-5
• Molecular Weight: 659.977
• Mol File: 260371-27-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pd(C₆H₅CC)(C₆H₅)2PC₆H₄CHNNC(O)C₆H₄NO₂(CAS DataBase Reference)
• NIST Chemistry Reference: Pd(C₆H₅CC)(C₆H₅)2PC₆H₄CHNNC(O)C₆H₄NO₂(260371-27-5)
• EPA Substance Registry System: Pd(C₆H₅CC)(C₆H₅)2PC₆H₄CHNNC(O)C₆H₄NO₂(260371-27-5)

Safety Data

• Hazardous Substances Data: 260371-27-5(Hazardous Substances Data)

Upstream product

• 238433-72-2 Pd(CH₃COO)(C₆H₅)2PC₆H₄CHNNC(O)C₆H₄NO₂ 
• 536-74-3 phenylacetylene 

Relevant articles and documents

Stable alkynyl palladium(II) and nickel(II) complexes with terdentate PNO and PNN hydrazone ligands

Chloro and acetato complexes of palladium(II) and nickel(II) with terdentate PNO acylhydrazonic ligands derived from 2-(diphenylphosphino)benzaldehyde have been synthesized and characterized. The acetato complexes are able to activate the C-H bond of terminal alkynes, giving stable alkynyl complexes, one of which has been X-ray characterized. The coordination chemistry of the new PNN ligand 2-(diphenylphosphino)benzaldehyde 2-pyridylhydrazone (HL6) has been also investigated and the X-ray crystal structure of the complex [Pd(HL6)Cl][PdL6Cl]Cl·2H2O is reported. Starting from the nickel(II) acetato complex of HL6, it has been possible to obtain a new stable alkynyl derivative.