26042-63-7

Basic information

• Product Name: Silver hexafluorophosphate
• Synonyms: SILVER(I)HEXAFLUOROPHOSPHATE;SILVER HEXAFLUOROPHOSPHATE;SILVER HEXAFLUOROPHOSPHATE (V);hexafluoro-phosphate(1-silver(1++);SILVER HEXAFLUOROPHOSPHATE, 99.99%;Silver(I) hexafluorophosphate(V);Silver hexafluorophosphate, 98%, -6 mesh;Silverhexafluorophosphate,99%
• CAS NO: 26042-63-7
• Molecular Formula: Ag*F₆P
• Molecular Weight: 252.83
• EINECS: 247-428-6
• Product Categories: Gold Catalysis;Silver AdditivesMetal and Ceramic Science;SilverCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;Chemical Synthesis;Salts;Silver Salts;SilverMetal and Ceramic Science;metal fluorophosphate complex;Silver Additives;Catalysis and Inorganic Chemistry;Chemical Synthesis;Gold Catalysis;Materials Science;Metal and Ceramic Science;Silver;Silver Salts
• Mol File: 26042-63-7.mol
• Article Data: 3

Chemical Properties

• Melting Point: 102 °C (dec.)(lit.)
• Appearance: Yellow to pale brown/Powder
• Solubility: Soluble in organic solvents such as benzene, toluene, and aceton
• Water Solubility: soluble
• Sensitive: Moisture Sensitive
• CAS DataBase Reference: Silver hexafluorophosphate(CAS DataBase Reference)
• NIST Chemistry Reference: Silver hexafluorophosphate(26042-63-7)
• EPA Substance Registry System: Silver hexafluorophosphate(26042-63-7)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45-36/39
• RIDADR: UN 3260 8/PG 2
• WGK Germany: 3
• F: 1-3-8-9
• TSCA: Yes
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 26042-63-7(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 26042-63-7 differently. You can refer to the following data:
1. Gold Catalysts — 21st Century ′Gold Rush′
2. It is commonly used as an oxidant forming silver metal. It is often used as a reagent in inorganic and organometallic chemistry. It is used in the preparation of engineering novel materials as well as in preparation of supra molecular Ag(I) complexes. It is used in the development of new catalysts, replacing halide ligands with the weakly coordinating hexafluorophosphate anion.

InChI:InChI=1/12Ag.6FH2O3P/c;;;;;;;;;;;;6*1-5(2,3)4/h;;;;;;;;;;;;6*(H2,2,3,4)/q12*+1;;;;;;/p-12

Upstream product

• 7726-95-6 bromine 
• 7440-22-4 silver 
• 7647-19-0 phosphorus pentafluoride 
• 11113-87-4 silver fluoride 
• 7647-19-0 phosphorus pentafluoride 
• 17084-13-8 potassium hexafluorophosphate 
• 7783-55-3 trifluorophosphane 
• 3109-63-5 tert-butylammonium hexafluorophosphate(V) 

Downstream Products

• 13478-20-1 trifluorophosphoric acid 
• 95464-87-2 silver difluorophosphinato 
• 118206-92-1 cis-{Pt(PPh₃)2(dmso)2}(PF₆)2 
• 113706-08-4 {iridium(1,3-bis(diphenylphosphino)propane)2}PF₆ 
• 101307-69-1 {Rh(C8H12)(η6-(C6H5)2CO)}PF6 
• 111267-04-0 tetrakis(triphenylphosphine)silver hexafluorophosphate 
• 111267-02-8 {Ag(P(C₆H₅)3)2}⁽¹⁺⁾*PF₆^(1-)={Ag(P(C₆H₅)3)2}PF₆ 
• 73887-77-1 [Ag(trimesitylarsine)2]PF₆ 
• 113706-02-8 cis-{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2}PF₆ 

Relevant articles and documents

Synthesis and characterization of luminescent zinc(II) complexes with a N,N-bidentate 1-pyridylimidazo[1,5-a]pyridine ligand

Ligand 2-(1-(pyridin-2-yl)imidazo[1,5-a]pyridin-3-yl)phenol (L) has been reacted in a 2:1 molar ratio with different Zn(Y)2nH2O salts, where Y represents a polyatomic anion (Y = ClO4-, NO3-, BF4-, PF6-). The X-ray structural analysis performed on two of the derivatives obtained, namely [Zn(L)2(ClO4)](ClO4)·H2O (1) and [Zn(L)2(CH3CN)2](BF4)2 (6), proves that as expected ligand L binds in a N,N-bidentate mode via the pyridine ring (Npy) and the pyridine-like nitrogen of the imidazo[1,5-a]pyridine skeleton (Nim). A spectroscopic investigation (including infrared, elemental analysis, 1H and 31P NMR, thermogravimetric analysis) has been performed on these species, allowing complete characterizations. A preliminary survey on their photophysical properties in the solid state was carried out: the complexes showing intense luminescence when excited with UV light (λexc = 421-469 nm) with λmax of emission in the blue-green range (468-500 nm) and moderate absolute photoluminescence quantum yields (PLQYs).

MANUFACTURING METHOD OF FLUORINATED HYDROCARBON

PROBLEM TO BE SOLVED: To provide a method for industrially advantageously manufacturing fluorinated hydrocarbon (3). SOLUTION: There is provided a method for manufacturing fluorinated hydrocarbon represented by the formula (3), including contacting a secondary or tertiary ether compound represented by the formula (1) and acid fluoride represented by the formula (2) in the presence of a silver salt in a hydrocarbon solvent. R1 and R2 are each independently a C1 to 3 alkyl group, R1 and R2 may bind to form a ring structure, R3 is H, a methyl group or an ethyl group, R4 and R5 are each independently a methyl group or an ethyl group. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPOandINPIT