260429-50-3Relevant academic research and scientific papers
Synthesis and X-ray structural characterization of dioxomolybdenum(VI) complexes with N'-(5-chloro-2-hydroxybenzylidene)-4-methylbenzohydrazide and N'(2-hydroxybenzylidene)-4-methylbenzohydrazide
Lei,Fu
, p. 65 - 70 (2012)
Two new dioxomolybdenum(VI) complexes, [MoO2(ClHm)(CH 3OH)] (I) and [MoO2(Hm)(CH3OH)] (II) with the hydrazone ligands H2ClHm and H2Hm derived from 4-methylbenzohy-drazide with 5-chlorosalicylaldehyde and salicylaldehyde, respectively, have been synthesized and structurally characterized by physicochemical methods and single-crystal X-ray determination. The crystal of I crystallizes in the triclinic space group $Πbar 1$$, with a = 7.839(2), b = 9.656(3), c = 11.548(4) A α = 88.885(3)°, β = 87.454(3)°, γ = 88.996(3)°, V = 873.0(5) A3, Z = 2, R 1 = 0.0292, wR 2 = 0.0685, S = 1.092. The crystal of II crystallizes in the triclinic space group $Πbar 1$$, with a = 7.780(2), b = 10.584(3), c = 10.628(3) A, α = 91.462(3)°, β = 104.818(3)°, γ = 103.288(3)°, V = 820.1(4) A3, Z = 2, R 1 = 0.0403, wR 2 = 0.0784, S = 1.065. An X-ray analysis indicates that the structures of both complexes are similar to each other. The molybdenum atom in each complex is in an octahedral coordination environment constructed by two oxo groups, an NO2 donor set of the hydrazone ligand, and one methanol O atom.
SYNERGISTIC FUNGICIDAL COMPOSITIONS INCLUDING HYDRAZONE DERIVATIVES AND COPPER
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Page/Page column 67, (2010/08/08)
The present invention relates to the use of mixtures containing hydrazone compounds and copper for controlling the growth of fungi.
