260445-16-7Relevant academic research and scientific papers
Mechanistic study of the ring-enlargement reaction of (3-oxa-2-silacyclopentyl)methyl radicals into 4-oxa-3-silacyclohexyl radicals. Evidence for a pentavalent silicon-bridging radical transition state in 1,2-rearrangement reactions of β-silyl radicals
Shuto, Satoshi,Sugimoto, Isamu,Abe, Hiroshi,Matsuda, Akira
, p. 1343 - 1351 (2007/10/03)
A mechanistic study was performed on a novel radical ring-enlargement reaction of (3-oxa-2-silacyclopentyl)methyl radicals into 4-oxa-3-silacyclohexyl radicals. Two pathways, one via a pentavalent silicon-bridging radical transition state (or intermediate
