26047-60-9Relevant academic research and scientific papers
Selective oxidation of acetylenic 1,4-diols with dioxiranes in comparison with the methyltrioxorhenium-hydrogen peroxide oxidant
D'Accolti, Lucia,Fiorentino, Michele,Fusco, Caterina,Crupi, Pasquale,Curci, Ruggero
, p. 8575 - 8578 (2004)
Dimethyldioxirane (DMD) and its trifluoro analog (TFD) were employed to achieve selectively the direct transformation of diol 3a and of diol 3b into the corresponding carbonyls. The results are compared with oxidations using methyltrioxorhenium (MTO)/85%
