260547-99-7

Basic information

• Product Name: (E)-1-(2-methylbutylthio)-1-[(4-methylphenyl)sulfonyl]propene
• Synonyms: (E)-1-(2-methylbutylthio)-1-[(4-methylphenyl)sulfonyl]propene
• CAS NO: 260547-99-7
• Molecular Weight: 298.47
• Mol File: 260547-99-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-(2-methylbutylthio)-1-[(4-methylphenyl)sulfonyl]propene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(2-methylbutylthio)-1-[(4-methylphenyl)sulfonyl]propene(260547-99-7)
• EPA Substance Registry System: (E)-1-(2-methylbutylthio)-1-[(4-methylphenyl)sulfonyl]propene(260547-99-7)

Safety Data

• Hazardous Substances Data: 260547-99-7(Hazardous Substances Data)

Upstream product

• 260548-02-5 1-(2-methylbutylthio)-1-[(4-methylphenyl)sulfonyl]propane 
• 260548-00-3 1-methyl-4-(2-methyl-butylsulfanylmethanesulfonyl)-benzene 
• 7569-26-8 chloromethyl p-tolylsulfone 
• 20089-07-0 2-methyl-1-butanethiol 
• 260548-04-7 1-chloro-1-(2-methylbutylthio)-1-[(4-methylphenyl)sulfonyl]propane 

Relevant articles and documents

Photochemical alkylation of ketene dithioacetal S,S-dioxides. An example of captodative olefin functionalization

Radical alkylation of some ketene dithioacetal S,S-dioxides failed through the tin hydride promoted chain process but was successfully performed through stoichiometric photochemical initiation, either by electron transfer or hydrogen abstraction. In the first case, alkyl radicals were produced from tetralkylstannanes (t-Bu-, i-Pr-, n-Bu-SnR3) via radical cation fragmentation, while in the second case these were produced from alkanes (cyclohexane, adamantane) by benzophenone triplet. When bulky radicals (t-Bu, adamantyl) were involved, the addition occurred with complete diastereoselectivity.