26059-45-0Relevant academic research and scientific papers
Thiol mediated 5-(π-endo)ortho vinyl radical cyclizations
Montevecchi, Pier Carlo,Navacchia, Maria Luisa
, p. 201 - 219 (2000)
The radical reaction of benzenethiol with alkynes 1a-o carried out at 154 °C affords a mixture of thiol/alkyne adduct 3 and benzothiophene 5, deriving from vinyl radical intermediates 2 through hydrogen abstraction and 5-(π-endo)(orthocyclization onto the
