260788-12-3

Upstream product

• 227015-10-3 1-tert-butoxycarbonyl-1-tosylhydrazine 
• 80-70-6 N,N,N',N'-tetramethylguanidine 

Downstream Products

• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 1360467-58-8 4-methylbenzenesulfinic acid 1,1,3,3-tetramethylguanidine salt 
• 1415714-56-5 N-t-butyloxycarbonyl-N’-(2-methyldec-5-yn-4-yl)-N’-p-toluenesulfonylhydrazine 
• 1415714-58-7 C₂₀H₂₄N₂O₄S₂ 
• 1415714-59-8 C₂₁H₂₅N₃O₄S 
• 1415714-60-1 C₂₀H₂₄N₄O₄S 
• 32884-74-5 3-[(4-methylphenyl)sulfanyl]-1H-indole 
• 1448723-23-6 tert-butyl 2-(naphthalene-2-carbonyl)-2-tosylhydrazinecarboxylate 
• 1448723-27-0 C₁₄H₁₃IN₂O₃S 
• 1448723-26-9 C₁₉H₂₁IN₂O₅S 
• 1448723-29-2 C₁₆H₁₆N₂O₅S 
• 1448723-28-1 C₂₁H₂₄N₂O₇S 
• 1448723-31-6 C₁₅H₁₃F₃N₂O₃S 
• 1448723-30-5 C₂₀H₂₁F₃N₂O₅S 

Relevant academic research and scientific papers

An unprecedented rearrangement of a 1,1-diprotected hydrazine derivative. Structure revision of a catalyst-containing by-product

Treatment of 1-Boc-1-tosyl-hydrazine with 1,1,3,3-tetramethylguanidine (TMG) gave rise to two products, one containing and the other not containing TMG. The latter was identified as 1-Boc-2-tosyl-hydrazine. This rearrangement provided useful insight into the nature of the first product that had previously been isolated and assigned an incorrect tentative structure. To rationalize the results a plausible mechanism via a common intermediate, involving TMG as a nucleophilic catalyst is proposed. A simpler procedure for the preparation of the starting material is also presented.

Sulfonyl carbazates as blowing agents

Sulfonyl carbazates containing at least one group of: wherein the oxygen and the sulphur atoms attach to various organic groups are useful as high temperature blowing agents for gas-expandable polymers. Additionally, novel polyfunctional and secondary