26079-84-5Relevant academic research and scientific papers
Structure of trans-diisothiocyanato(ethoxo)oxo-bis(triphenylphosphine)rhenium(V) complex
Battistuzzi, Raffaele,Saladini, Monica
, p. 114 - 117 (2000)
The title compound consists of [ReO(NCS)2(OEt)(PPh3)2] units in which the rhenium(V) center shows a slightly distorted octahedral coordination. The two N-coordinated NCS- groups are trans to each other, as the Re=O and the Re-OEt units. The Re=O and Re-OEt bond lengths [1.682(10) and 1.871(10) ?, respectively] and the geometry about the ethoxide oxygen atom indicate that in both cases M-O ligation has a considerable degree of multiple bond. (C) 2000 Elsevier Science S.A.
