261172-34-3

Basic information

• Product Name: (S)-5-Allyl-1-[(S)-1-(2-methoxy-phenyl)-ethyl]-pyrrolidin-2-one
• Synonyms: (S)-5-Allyl-1-[(S)-1-(2-methoxy-phenyl)-ethyl]-pyrrolidin-2-one
• CAS NO: 261172-34-3
• Molecular Weight: 259.348
• Mol File: 261172-34-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-5-Allyl-1-[(S)-1-(2-methoxy-phenyl)-ethyl]-pyrrolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-5-Allyl-1-[(S)-1-(2-methoxy-phenyl)-ethyl]-pyrrolidin-2-one(261172-34-3)
• EPA Substance Registry System: (S)-5-Allyl-1-[(S)-1-(2-methoxy-phenyl)-ethyl]-pyrrolidin-2-one(261172-34-3)

Safety Data

• Hazardous Substances Data: 261172-34-3(Hazardous Substances Data)

Upstream product

• 261172-32-1 (S)-5-Allyl-1-[(S)-1-(2-hydroxy-phenyl)-ethyl]-pyrrolidin-2-one 
• 74-88-4 methyl iodide 
• 261172-30-9 1-[(S)-1-(2-Hydroxy-phenyl)-ethyl]-pyrrolidine-2,5-dione 
• 261172-31-0 4-methyl-1,9a-dihydro-2H,4H-9-oxa-3a-aza-cyclopenta[b]naphthalen-3-one 
• 133511-37-2 2-[(1S)-1-aminoethyl]phenol 

Downstream Products

• 261172-35-4 {(S)-1-[(S)-1-(2-Methoxy-phenyl)-ethyl]-5-oxo-pyrrolidin-2-yl}-acetaldehyde 
• 261172-40-1 (R)-1-[(S)-1-(2-Methoxy-phenyl)-ethyl]-5-(4-oxo-decyl)-pyrrolidin-2-one 
• 261172-41-2 1-{(R)-1-[(S)-1-(2-Methoxy-phenyl)-ethyl]-pyrrolidin-2-yl}-decan-4-one 
• 261172-39-8 (S)-1-[(S)-1-(2-Methoxy-phenyl)-ethyl]-5-((E)-4-oxo-dec-2-enyl)-pyrrolidin-2-one 
• 261172-36-5 (S)-1-[(S)-1-(2-Methoxy-phenyl)-ethyl]-5-((E)-4-oxo-hept-2-enyl)-pyrrolidin-2-one 
• 261172-37-6 (R)-1-[(S)-1-(2-Methoxy-phenyl)-ethyl]-5-(4-oxo-heptyl)-pyrrolidin-2-one 
• 261172-38-7 1-{(R)-1-[(S)-1-(2-Methoxy-phenyl)-ethyl]-pyrrolidin-2-yl}-heptan-4-one 

Relevant articles and documents

Asymmetric synthesis of (-)-indolizidines 167B and 209D based on stereocontrolled allylation of a chiral tricyclic N-acyl-N,O-acetal

(Formula presented) The tricyclic N-acyl-N,O-acetal incorporating (S)-2-(1-aminoethyl)phenol as a chiral auxiliary underwent TiCl4-mediated allylation to give the chiral (5S)-allylpyrrolidinone with retention of configuration in high yield and diastereoselectivity. On the bases of this methodology, the asymmetric syntheses of the dendrobatid alkaloids (-)-indolizidines 167B and 209D were achieved.