26119-44-8

Basic information

• Product Name: Cyclopropanecarboxaldehyde, 2,2-dimethyl-
• Synonyms: 2,2-Dimethylcyclopropylcarboxaldehyde;2-Formyl-1,1-dimethyl-cyclopropan;1.1-Dimethyl-2-formyl-cyclopropan;2,2-Dimethyl-cyclopropancarbaldehyd;Cyclopropanecarboxaldehyde,2,2-dimethyl;2,2-dimethylcyclopropanecarboxaldehyde;2,2-dimethylcyclopropanecarbaldehyde
• CAS NO: 26119-44-8
• Molecular Formula: C6H10O
• Molecular Weight: 98.1448
• Mol File: 26119-44-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclopropanecarboxaldehyde, 2,2-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanecarboxaldehyde, 2,2-dimethyl-(26119-44-8)
• EPA Substance Registry System: Cyclopropanecarboxaldehyde, 2,2-dimethyl-(26119-44-8)

Safety Data

• Hazardous Substances Data: 26119-44-8(Hazardous Substances Data)

Upstream product

• 5722-11-2 rac-2,2-dimethylcyclopropanecarbonitrile 

Downstream Products

• 69709-29-1 C₁₉H₂₀ 
• 95188-06-0 N-(2,2-dimethylcyclopropyl)methylaniline 
• 95188-04-8 N-(2,2-dimethylcyclopropyl)methylidineaniline 

Relevant articles and documents

NADH MODELS-19 CYCLOPROPANE RING AS A CHEMICAL PROBE IN THE STUDY OF THE MECHANISM OF HYDROGEN TRANSFER BY 1,4-DIHYDROPYRIDINE DERIVATIVES

N-(Cyclopropylmethylene)phenylamines (1a-c), cyclopropyl 2-pyridyl ketones (5a-c) and ethyl cyclopropylmethylenepyruvate (14) have been subjected to reduction by 1,4-dihydropyridines in the presence of magnesium ions, and by tin hydrides.The reactions with 1,4-dihydropyridines do not involve cleavage of the three-membered ring in the reduction step.The observed acyclic product from 2-pyridyl 2,2-dimethylcyclopropyl ketone (5b) is a consequence of ring cleavage prior to reduction of the carbonyl function.In contrast, reduction of 1a-c and 5a-c by tin hydrides leads to products in which the cyclopropane moiety has undergone ring-opening.These findings support a hydride transfer mechanism for reductions with NADH models.