261350-35-0

Upstream product

• 71098-88-9 N-phenylselanylphthalimide 
• 261350-34-9 6-(4,4-dimethylcyclopent-1-enyl)hept-2E-enoic acid 
• 261350-33-8 4-(4,4-dimethylcyclopent-1-enyl)pentan-1-al 
• 261350-29-2 4-(4,4-dimethylcyclopent-1-enyl)pentan-1-ol 
• 261350-30-5 methyl 6-(4,4-dimethylcyclopent-1-enyl)hept-2E-enoate 
• 261350-32-7 t-butyl[4-(4,4-dimethylcyclopent-1-enyl)pentyloxy]dimethylsilane 
• 261350-31-6 5-(t-butyldimethylsilanyloxy)-2-(4,4-dimethylcyclopent-1-enyl)pentan-1-ol 
• 261350-27-0 methyl 5-(t-butyldimethylsilanyloxy)-2-(4,4-dimethylcyclopent-1-enyl)pentanoate 
• 261350-28-1 5-(t-butyldimethylsilanyloxy)-2-(4,4-dimethylcyclopent-1-enyl)pentyl toluene-4-sulfonate 

Relevant academic research and scientific papers

Tandem cyclisations involving α-ketenyl alkyl radicals. New syntheses of the natural triquinanes pentalenene and modhephene

New synthetic approaches to the angular and propellane sesquiterpene triquinanes (±)-pentalenene 2 and (±)-modhephene 3, respectively, are described. The syntheses are based on tandem cyclisations involving α-ketene alkyl radical intermediates produced fr

A new synthesis of pentalenene using a novel tandem cyclisation involving ketene radical intermediates

A new approach to the synthesis of the angular triquinane (±)- pentalenene, based on sequential 5-exo-trig and 5-exo-dig radical cyclisations involving ketene intermediates produced from an α,β- unsaturated acyl radical precursor, is described.