2615-18-1

Basic information

• Product Name: 1 4-BIS(TRIETHOXYSILYL)BENZENE 96
• Synonyms: 1 4-BIS(TRIETHOXYSILYL)BENZENE 96;1,4-Phenylenebis(triethoxysilane);1,4-Bis(triethoxysilyl)benzene 96%;Benzene,1,4-bis(triethoxysilyl)-;Bis(triethoxysilyl)benzene
• CAS NO: 2615-18-1
• Molecular Formula: C₁₈H₃₄O₆Si₂
• Molecular Weight: 402.633
• Product Categories: Organometallic Reagents;Organosilicon;Trialkoxysilanes
• Mol File: 2615-18-1.mol
• Article Data: 7

Chemical Properties

• Melting Point: >0°C
• Boiling Point: 130-133 °C0.5 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.015 g/mL at 25 °C(lit.)
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: n20/D 1.456(lit.)
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: 1 4-BIS(TRIETHOXYSILYL)BENZENE 96(CAS DataBase Reference)
• NIST Chemistry Reference: 1 4-BIS(TRIETHOXYSILYL)BENZENE 96(2615-18-1)
• EPA Substance Registry System: 1 4-BIS(TRIETHOXYSILYL)BENZENE 96(2615-18-1)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• WGK Germany: 3
• Hazardous Substances Data: 2615-18-1(Hazardous Substances Data)

Usage

Chemical Properties

Clear colorless liquid

Uses

Different sources of media describe the Uses of 2615-18-1 differently. You can refer to the following data:
1. 1,4-Bis(triethoxysilyl)benzene (BTEB) is a silicon-based nucleophile shown to be reactive in Pd-catalyzed cross-coupling reactions. It is extensively used as a precursor in the synthesis of a variety of periodic mesoporous organosilicas (PMOs).
2. suzuki reaction

InChI:InChI=1/C18H34O6Si2/c1-7-19-25(20-8-2,21-9-3)17-13-15-18(16-14-17)26(22-10-4,23-11-5)24-12-6/h13-16H,7-12H2,1-6H3

Upstream product

• 78-10-4 tetraethoxy orthosilicate 
• 106-37-6 1.4-dibromobenzene 
• 624-38-4 para-diiodobenzene 
• 51833-37-5 phenyl-1,4-bis(magnesium chloride) 

Downstream Products

• 1361341-82-3 1,4-bis(tris(4-bromophenyl)silyl)benzene 
• 1226916-77-3 4-trimethylsilyl-phenyltriethoxysilane 
• 857373-25-2 1,4-bis[ethoxydi(prop-2-enyl)silyl]benzene 

Relevant articles and documents

An alternate route for the synthesis of hybrid mesoporous organosilica with crystal-like pore walls from allylorganosilane precursors

The bridged allylorganosilanes 1,4-bis(diallylethoxysilyl)benzene and 1,4-bis(triallylsilyl)benzene are presented as new precursors for the surfactant-assisted synthesis of ordered mesoporous organosilica with pore walls having crystal-like molecular-scal

Meerwein's reagent mediated, significantly enhanced nucleophilic fluorination on alkoxysilanes

We developed a new facile method to fluorosilanes from alkoxysilanes using Meerwein's reagent. Our protocol afforded fluorosilanes in excellent yields in various organic solvents including acetonitrile under mild reaction conditions at room temperature. We also proposed a reaction mechanism with the probable silyloxonium intermediates. Georg Thieme Verlag Stuttgart · New York.

Hybrid organic-inorganic adsorbents

The present invention relates generally to hybrid organic-inorganic adsorbents for decontamination of fluids. Bridged poysilsesquioxanes are a family of hybrid organic-inorganic materials prepared by sol-gel processing of monomers that contain a variable organic bridging group and two or more trifunctional silyl groups. Specifically, the present invention relates to dipropylenedisulfide-co-phenylene-bridged polysilsesquioxane compositions, methods of making dipropylenedisulfide-co-phenylene-bridged polysilsesquioxanes, and methods of use of dipropylenedisulfide-co-phenylene-bridged polysilsesquioxanes. The present invention discloses properties of dipropylenedisulfide-co-phenylene-bridged polysilsesquioxanes that include high ligand loading, increased surface area, and increased porosity. These properties make dipropylenedisulfide-co-phenylene-bridged polysilsesquioxanes excellent adsorbents for decontamination of fluids for use in environmental and industrial processes.