2615-23-8Relevant articles and documents
Siloxa-bridged-cyclophanes featuring benzene, thiophene and pyridine units
Moores, Audrey,Defieber, Christian,Mezailles, Nicolas,Maigrot, Nicole,Ricard, Louis,Le Floch, Pascal
, p. 994 - 999 (2007/10/03)
Two octamethyldisiloxa-bridged [3.3]cyclophanes (1 and 2) and a dodecamethyltrissiloxa-bridged [3.3.3]-cage compound (3) were prepared by hydrolysis of the chlorosilyl monomers. This general route was also employed for the preparation of two octamethyldisiloxa-bridged [3.3]heterophanes featuring two thiophene (14) or pyridine (17) moities.
Process for producing aromatic-containing silicone compounds
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, (2008/06/13)
An improved process for producing an aromatic containing silicon compound comprising reacting an aromatic organic compound of the formula RXa with a silicon compound of the formula Rb ' Si Z4-b in the presence of molar quantities of Mg and from 0.5 to up to 1 mole of a promoter which is preferably tetrahydrofuran per mole of the aromatic compound where R is preferably phenylene, X is chloro, a is 2, R' is preferably methyl, Z is alkoxy of 1 to 8 carbon atoms and b is equal to 2.