261526-74-3Relevant academic research and scientific papers
Tandem cross-dimerisation/oxonia-cope reaction of carbonyl compounds to homoallylic esters and lactones
Zou, Yue,Ding, Changming,Zhou, Lijun,Li, Zhiming,Wang, Quanrui,Schoenebeck, Franziska,Goeke, Andreas
supporting information; experimental part, p. 5647 - 5651 (2012/07/13)
Conceptually different: This allyltransfer reaction is catalyzed by Lewis acids (LAs) and proceeds atom-economically by disproportionation of the carbonyl groups through organized oxonia-Cope transition states (see scheme). A stereoselective [n+4] ring enlargement leads to a variety of macrolides with 9- to 16-membered rings. Copyright
