261717-41-3

Basic information

• Product Name: (E)-HEPTENYLDIISOPROPYLSILANOL
• Synonyms: (E)-HEPTENYLDIISOPROPYLSILANOL
• CAS NO: 261717-41-3
• Molecular Formula: C₁₃H₂₈OSi
• Molecular Weight: 228.45
• Mol File: 261717-41-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 88°C/0.1mmHg
• Flash Point: 129.379°C
• Appearance: /
• Density: 0.844g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.448
• PKA: 14.32±0.53(Predicted)
• CAS DataBase Reference: (E)-HEPTENYLDIISOPROPYLSILANOL(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-HEPTENYLDIISOPROPYLSILANOL(261717-41-3)
• EPA Substance Registry System: (E)-HEPTENYLDIISOPROPYLSILANOL(261717-41-3)

Safety Data

• TSCA: No
• Hazardous Substances Data: 261717-41-3(Hazardous Substances Data)

Usage

General Description

(E)-HEPTENYLDIISOPROPYLSILANOL is a chemical compound with a molecular formula C15H32OSi. It is a silanol derivative with a heptenyl group bound to the silicon atom, and two isopropyl groups. (E)-HEPTENYLDIISOPROPYLSILANOL is used as a chemical intermediate in organic synthesis and in the production of various silicone-based materials. It has potential use in the manufacturing of adhesives, sealants, and coatings. It may also be used in the synthesis of pharmaceuticals and agrochemicals. (E)-HEPTENYLDIISOPROPYLSILANOL is a colorless to pale yellow liquid with a characteristic odor, and it should be handled and used with appropriate safety measures in place.

InChI:InChI=1/C13H28OSi/c1-6-7-8-9-10-11-15(14,12(2)3)13(4)5/h10-14H,6-9H2,1-5H3/b11-10+

Upstream product

• 90-14-2 1-Iodonaphthalene 
• 628-71-7 1-Heptyne 
• 2227-29-4 chlorodiisopropylsilane 
• 144-55-8 sodium hydrogencarbonate 
• 261717-43-5 (E)-diisopropyl-(1-heptenyl)silyl chloride 

Downstream Products

• 10201-58-8 (E)-1-heptenylbenzene 

Relevant articles and documents

Fluoride-Promoted Cross-Coupling Reactions of Alkenylsilanols. Elucidation of the Mechanism through Spectroscopic and Kinetic Analysis

The mechanism of the palladium-catalyzed cross-coupling reaction of (E)-dimethyl-(1-heptenyl)-silanol ((E)-1) and of (E)-diisopropyl-(1-heptenyl)silanol ((E)-2) with 2-iodothiophene has been investigated through spectroscopic and kinetic analysis. A commo

Cross-coupling reaction of organosilicon nucleophiles

Improved methods for generating a —C—C— bond by cross-coupling of a transferable group with an acceptor group. The transferable group is a substituent of an organosilicon nucleophile and the acceptor group is provided as an organic electrophile. The reaction is catalyzed by a Group 10 transition metal complex (e.g., Ni, Pt or Pd), particularly by a palladium complex. Certain methods of this invention use improved organosilicon nucleophiles which are readily prepared, can give high product yields and exhibit high stereo selectivity. Methods of this invention employ activating ions such as halides, hydroxide, hydride and silyloxides. In specific embodiments, organosilicon nucleophilic reagents of this invention include siloxanes, particularly cyclic siloxanes. The combination of the cross-coupling reactions of this invention with ring-closing metathesis, hydrosilylation and intramolecular hydrosilylation reactions provide useful synthetic strategies that have wide application.