261907-86-2Relevant academic research and scientific papers
Synthesis of (Boryl)(silyl)iminomethanes by Insertion of Isonitriles into Silicon-Boron Bonds
Suginome, Michinori,Fukuda, Takeshi,Nakamura, Hiroshi,Ito, Yoshihiko
, p. 719 - 721 (2008/10/08)
The insertion of alkyl and aryl isonitriles into the silicon-boron bond of silylboranes proceeded thermally to provide (boryl)(silyl)iminomethanes in moderate-to-good yields. The (boryl)(silyl)iminomethane reacted with borane (BH3) to give the corresponding borane complex in good yield, whose crystal structure was determined by a single-crystal X-ray analysis.
