261926-98-1

Basic information

• Product Name: C₄₁H₃₃O₃P₂Rh
• CAS NO: 261926-98-1
• Molecular Weight: 738.564
• Mol File: 261926-98-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: C₄₁H₃₃O₃P₂Rh(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₁H₃₃O₃P₂Rh(261926-98-1)
• EPA Substance Registry System: C₄₁H₃₃O₃P₂Rh(261926-98-1)

Safety Data

• Hazardous Substances Data: 261926-98-1(Hazardous Substances Data)

Upstream product

• 161265-03-8 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene 

Relevant articles and documents

A silica-supported, switchable, and recyclable hydroformylation - Hydrogenation catalyst

A homogeneous hydroformylation catalyst, designed to produce selectively linear aldehydes, was covalently tethered to a polysilicate support. The immobilized transition-metal complex [Rh(A)CO]+ (1+), in which A is N-(3-trimethoxysila

Tandem hydroformylation/hydrogenation of alkenes to normal alcohols using Rh/Ru dual catalyst or Ru single component catalyst

The catalyst system for tandem hydroformylation/hydrogenation of terminal alkenes to the corresponding homologated normal alcohol was developed. The reaction mechanism for the Rh/Ru dual catalyst was investigated by real-time IR monitoring experiments and 31P NMR spectroscopy, which proved the mutual orthogonality of Rh-catalyzed hydroformylation and Ru-catalyzed hydrogenation. Detailed investigation about Ru-catalyzed hydrogenation of undecanal under H2/CO pressure clarified different kinetics from the hydrogenation under H2 and gave a clue to design more active hydrogenation catalysts under H2/CO atmosphere. The solely Ru-catalyzed normal selective hydroformylation/hydrogenation is also reported.