262614-99-3

Upstream product

• 262614-82-4 Acetic acid (2R,4S,6R,8S,10S)-8-[2-(2-bromo-benzyloxy)-ethyl]-2-(4-methoxy-benzyloxymethyl)-10-(2-trimethylsilanyl-ethoxymethoxy)-1,7-dioxa-spiro[5.5]undec-4-yl ester 
• 262614-84-6 (2R,4S,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-2-(4-methoxy-benzyloxymethyl)-4-methyl-10-(2-trimethylsilanyl-ethoxymethoxy)-1,7-dioxa-spiro[5.5]undecan-4-ol 
• 262614-83-5 (2R,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-2-(4-methoxy-benzyloxymethyl)-10-(2-trimethylsilanyl-ethoxymethoxy)-1,7-dioxa-spiro[5.5]undecan-4-one 
• 262614-97-1 (2R,4S,6S,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-2-(4-methoxy-benzyloxymethyl)-10-(2-trimethylsilanyl-ethoxymethoxy)-1,7-dioxa-spiro[5.5]undecan-4-ol 
• 194342-86-4 Acetic acid (2R,4S,6R,8S,10S)-8-[2-(2-bromo-benzyloxy)-ethyl]-10-hydroxy-2-(4-methoxy-benzyloxymethyl)-1,7-dioxa-spiro[5.5]undec-4-yl ester 
• 76513-69-4 (2-trimethylethylsilylethoxy)methyl chloride 
• 69739-34-0 t-butyldimethylsiyl triflate 

Downstream Products

• 1025954-24-8 [(2R,4S,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-4-(tert-butyl-dimethyl-silanyloxy)-4-methyl-10-(2-trimethylsilanyl-ethoxymethoxy)-1,7-dioxa-spiro[5.5]undec-2-yl]-acetaldehyde 
• 262615-00-9 [(2S,4S,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-4-(tert-butyl-dimethyl-silanyloxy)-4-methyl-10-(2-trimethylsilanyl-ethoxymethoxy)-1,7-dioxa-spiro[5.5]undec-2-yl]-acetonitrile 
• 262614-87-9 1-[(2R,4S,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-4-(tert-butyl-dimethyl-silanyloxy)-4-methyl-10-(2-trimethylsilanyl-ethoxymethoxy)-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one 
• 262614-86-8 1-[(2S,4S,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-4-(tert-butyl-dimethyl-silanyloxy)-4-methyl-10-(2-trimethylsilanyl-ethoxymethoxy)-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-ol 
• 262614-93-7 (2R,4S,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-4-(tert-butyl-dimethyl-silanyloxy)-4-methyl-10-(2-trimethylsilanyl-ethoxymethoxy)-2-((Z)-2-trimethylsilanyloxy-but-2-enyl)-1,7-dioxa-spiro[5.5]undecane 
• 262614-94-8 C₇₉H₁₂₅BrSi₄O₁₄CH₂ 
• 262614-85-7 (2R,4S,6R,8S,10S)-8-[2-(2-Bromo-benzyloxy)-ethyl]-4-(tert-butyl-dimethyl-silanyloxy)-2-iodomethyl-4-methyl-10-(2-trimethylsilanyl-ethoxymethoxy)-1,7-dioxa-spiro[5.5]undecane 

Relevant academic research and scientific papers

A modular approach to marine macrolide construction. 3. Enantioselective synthesis of the C1-C28 sector of spongistatin 1 (altohyrtin A).

[structure: see text] A completely stereocontrolled approach to assembly of the major C1-C28 subunit of spongistatin 1 (altohyrtin A) is described. Key steps included the control of two asymmetric aldols by means of Fujita-Nagao (chiral N-acyl-1,3-thiazol