262852-30-2Relevant academic research and scientific papers
An unusual observation in the rhodium carbenoids: [1,4]-migration in the sugar-derived α-diazo-β-ketoesters
Desai, Vijaya N.,Saha, Nabendu N.,Dhavale, Dilip D.
, p. 147 - 151 (2007/10/03)
In competition with [1,2]-migration, [2,3]-sigmatropic rearrangement and C-H insertion, product formation via an unusual [1,4]-migration is also found to be a prominent process in the rhodium carbenoids derived from sugar α-diazo-β-keto esters 2a-d. The R
