2630-68-4Relevant academic research and scientific papers
Desymmetrization of hydrazinocyclohexadienes: A new approach for the synthesis of polyhydroxylated aminocyclohexanes
Errastl, Gauthier,Kounde, Cyrille,Mlrguet, Olivier,Lecourt, Thomas,Micouln, Laurent
supporting information; experimental part, p. 2912 - 2915 (2009/12/06)
Hydrazlnocyclohexadlenes, easily prepared by an ene-reactlon between commercially available azodlcarboxylate reagents and cyclohexadlene, are Interesting substrates for desymmetrlzatlon reactions. Under Sharpless asymmetric dihydroxylation conditions, the
Stereocontrolled Preparation of Cyclohexane Amino Alcohols Utilising a Modified Mitsunobu Reaction
Sammes, Peter G.,Thetford, Dean
, p. 655 - 661 (2007/10/02)
A method for the introduction of amino groups into aliphatic systems is described.Cyclohex-2-enol reacts with aromatic diacylamines under Mitsunobu reaction conditions to give either N-alkylated or O-alkylated products in a controlled, predictable manner.
NEW ROUTES TO CIS-1,2-HYDROXYAMINES AND RELATED SYSTEMS
Sammes, Peter G.,Thetford, Dean
, p. 2275 - 2278 (2007/10/02)
Use of modified Mitsunobu reactions followed by intramolecular cyclisations have been used to prepare cis-1,2-hydroxyamines, cis-1,3-hydroxyamines, 1,2,3-dihydroxyamines and 1,2,3-diaminoalcohols from allylic alcohols
Synthetic Study and Conformational Analysis of O-Benzylated Aminocyclitols
Kiso, Makoto,Kobayashi, Toshiyuki,Hasegawa, Akira
, p. 419 - 426 (2007/10/02)
DL-(1,3/2)-3-Acetamido-1,2-di-O-benzylcyclohex-4-enediol (IIIa) and DL-(1,3/4)-1-acetamido-3,4-di-O-benzylcyclohex-5-enediol (IIIb) were synthesized from DL-trans-1,2-di-O-benzylcyclohex-3-enediol (I) via the corresponding azide derivatives (IIa-b) prepar
