2632-83-9

Upstream product

• 1558-33-4 chloromethylmethyldichlorosilane 
• 18246-09-8 (chloromethyl)methylphenylsilane 
• 108-86-1 bromobenzene 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 5920-88-7 (chloromethyl)ethoxymethylphenylsilane 
• 5927-27-5 1,3-bis-chloromethyl-1,3-dimethyl-1,3-diphenyl-disiloxane 
• 18246-09-8 (chloromethyl)methylphenylsilane 
• 1628-03-1 1,3-dimethyl-1,3-diphenyl-1,3-disilacyclobutane 
• 128396-41-8 C₂₄H₃₁Cl₃O₃Si₄ 
• 375388-61-7 chloromethyl-methyl-phenyl-vinyl-silane 
• 560132-06-1 (E)-(buta-1,3-dien-1-yl)(chloromethyl)methyl(phenyl)silane 
• 912459-64-4 N-methyl-N-(methylphenylmethoxysilylmethyl)acetamide 
• 560132-09-4 (E)-2-methyl-2-phenyl-2-silahexa-3,5-dien-1-ol 
• 560132-12-9 (E)-2-methyl-2-phenyl-2-silahexa-3,5-dien-1-yl acrylate 
• 61676-43-5 γ-Hydroxypropyl-benzyl-dimethylsilan 
• 133511-55-4 methylphenyl(chloromethyl)(3-hydroxypropyl)silane 
• 63667-89-0 2-benzyl-2-methyl-[1,2]oxasilolane 

Relevant academic research and scientific papers

Palladium-Catalyzed β-Elimination of Aminoboranes from (Aminomethylsilyl)boranes Leading to the Formation of Silene Dimers

Silylboronic esters bearing a N,N-dialkylaminomethyl group on the silicon atoms were synthesized and used in palladium-catalyzed reactions. Five silylboronic esters were synthesized through a reaction of the [(N,N-dialkylaminomethyl)diorganosilyl]lithiums

Preparation of sila-functional 3-sila-1-thiacyclohexanes

First sila-functional heterocycles 7 and 9 with Si and S atoms in 1,3-position bearing the reactive X group at silicon (X = i-PrO, F) were readily prepared from the corresponding phenyl-protected cycle 6 in good yields via Ph-Si bond cleavage by electroph

Highly diastereoselective intramolecular Diels-Alder reaction of chiral silatrienes

New Si-chiral 2-silahexa-3,5-dienyl acrylates were prepared in six steps from dichloro(chloromethyl)methylsilane. The EtAlCl2 catalysed intramolecular Diels-Alder reaction of these compounds gave chiral 4-sila-4a,7,8,8a-tetrahydroisochroman-1-ones in good yield. Very good diastereoselectivity was observed for a silatriene bearing a methyl and a 2-methoxyphenyl substituent on the chiral silicon atom.

Diastereoselective synthesis of 4-sila-3,4,4a,5-tetrahydro-2H-isoquinolin-1-ones through intramolecular Diels-Alder reaction of chiral silatrienes

New Si-chiral N-2-silabut-3-enylpyran-2-one-6carboxamides were prepared in four steps from dichloro(chloro-methyl)methylsilane. The thermal inverse electron demand intra-molecular Diels-Alder reaction of these compounds gave 4-sila3,4,4a,5-tetrahydro-2H-isoquinolin-1-ones. Moderate diastereoselectivity was observed for a silatriene bearing a methyl and a cyclohexyl substituent on the chiral silicon atom. The intermediate tricyclic adduct of this reaction was also isolated.

Fungicidal 1,2,4-triazole derivatives

Silicon-containing 1,2,4-triazoles having broad-spectrum fungicidal activity have been discovered.

Fungicidal imidazole derivatives

Silicon-containing imidazoles having broad-spectrum fungicidal activity have been discovered.

Synthesis and Properties of (Hydroxymethyl)diorganylsilanes

The synthesis of the (hydroxymethyl)diorganylsilanes R1R2Si(H)CH2OH (4a: R1 = R2 = CH3, 2-silaisobutanol; 4b: R1 = CH3, R2 = C6H5; 4c: R1 = R2 = C6H5) is achieved by the reaction of R1R2Si(Cl)CH2Cl (2a - c) with AcOH/NEt3 to R1R2Si(OAc)CH2OAc (3a - c), fo

SILAETHENE II. DARSTELLUNG UND CHARAKTERISIERUNG VON 1,3-DISILACYCLOBUTANEN

1,3-Disilacyclobutanes of the types R1R2SiSiR1R2 are prepared (a) by ring synthesis from chloromethylchlorosilanes R1R2Si(CH2Cl)Cl, (b) by thermolysis of monosilacyclobutanes , and (c) by substitution of chlorine with alkyl groups in SiCl-containing 1,3-disilacyclobutanes, obtained by procedures (a) or (b).The compounds have been characterized by analytical and spectroscopic investigations.The synthetic methods are critically compared.