26322-14-5 Usage
Chemical Properties
Dicetyl peroxydicarbonate is a white powder with faint odor. It
presents a bulk density of 0.6 g/cm3 andmelting point of 52°C.
It is sensitive to heat and its storage must be done so with
stringent temperature control measures. Its explosion hazard is
mitigated by mixing the peroxide with inert solid. It decomposes
violently or explosively at temperatures 0–10°C owing to
self-accelerating exothermic decomposition. Several recorded
explosions were due to shock, heat, or friction; amines and
certain metals can cause accelerated decomposition (12d).
Uses
Dicetyl peroxydicarbonate is an imitator for the copolymerization
of vinyl chloride, vinylidene chloride, acrylates, and
methacrylates. No information was located for this compound.
Decomposition or combustion products include carbon
dioxide, carbon monoxide, and hexadecanol.
General Description
Dicetyl peroxydicarbonate is sensitive to heat. Storage of Dicetyl peroxydicarbonate must be done so with stringent temperature control measures. It's explosion hazard is also mitigated by mixing the peroxide with inert solid.
Reactivity Profile
Dicetyl peroxydicarbonate decomposes violently or explosively at temperatures 0-10° C. owing to self-accelerating exothermic decomposition; Several explosions were due to shock, heat or friction; amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156].
Check Digit Verification of cas no
The CAS Registry Mumber 26322-14-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,6,3,2 and 2 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 26322-14:
(7*2)+(6*6)+(5*3)+(4*2)+(3*2)+(2*1)+(1*4)=85
85 % 10 = 5
So 26322-14-5 is a valid CAS Registry Number.
InChI:InChI=1/C34H66O6/c1-3-5-7-9-11-13-15-17-19-21-23-25-27-29-31-37-33(35)39-40-34(36)38-32-30-28-26-24-22-20-18-16-14-12-10-8-6-4-2/h3-32H2,1-2H3
26322-14-5Relevant articles and documents
Synthesis and Properties of Dialkyl Peroxydicarbonates Based on Fractions of Fatty Alcohols
Fomin, V. A.
, p. 1221 - 1224 (2007/10/03)
Conditions for synthesis of dialkyl peroxydicarbonates were determined. The kinetics of thermal decomposition of the peroxides in organic solvents were studied. The possibility of using these compounds as initiators for polymerization of vinyl chloride wa
