2633-60-5

Usage

InChI:InChI=1/C13H18Si/c1-4-11-14(3,12-5-2)13-9-7-6-8-10-13/h4-10H,1-2,11-12H2,3H3

Upstream product

• 346713-20-0 allylsamarium bromide 
• 149-74-6 dichloromethylphenylsilane 
• 106-95-6 allyl bromide 
• 112945-35-4 allylchloro(methyl)phenylsilane 
• 2622-05-1 allylmagnesium bromide 

Downstream Products

• 18547-52-9 bis-(2-dimethoxythiophosphorylsulfanyl-propyl)-methyl-phenyl-silane 
• 1292360-20-3 (Ph)(Me)Si((CH₂)3B(OH)2)2 
• 1292360-21-4 (Ph)(Me)Si((CH₂)3OH)2 
• 20795-53-3 3-phenylcyclohexanone 
• 1401456-54-9 C₂₁H₄₂Si₃ 
• 1401456-69-6 [PdCl₂{(Ph₂PCH₂)₂N(C₆H₄-4-SiMe(CH₂CH₂CH₂SiEtMe₂)₂)}] 
• 1401456-60-7 C₄₇H₆₅NP₂Si₃ 
• 50694-31-0 1-methyl 1-phenyl 1-silacyclopent-3-ene 
• 132816-63-8 3-Methyl-3-phenyl-3-sila-bicyclo[3.2.0]heptane 
• 18505-61-8 4-Methyl-4-phenyl-4-sila-heptylen-(1.7)-dithioacetat 
• 18412-66-3 1.7-Dimercapto-4-methyl-4-phenyl-4-sila-heptan 

Relevant academic research and scientific papers

Zinc mediated allylations of chlorosilanes promoted by ultrasound: Synthesis of novel constrained sila amino acids

A simple, fast and efficient method for allylation and propargylation of chlorosilanes through zinc mediation and ultrasound promotion is reported. As a direct application of the resulting bis-allylsilanes, three novel, constrained sila amino acids are prepared for the first time. The design and synthesis of the constrained sila analogue of GABA (γ-amino butyric acid) is a highlight of this work. This journal is the Partner Organisations 2014.

Selective mono- and di-allylation and allenylation of chlorosilanes using indium

Allyl and allenyl groups have been introduced into silicon systems by the allylation and allenylation of chlorosilanes using allyl bromide or propargyl bromide with indium. The allylation of chlorosilanes afforded a variety of aryl, aralkyl, and alkenyl substituted allylsilanes. By applying this method, the reactions of 1-bromo-3-methylbut-2-ene, 3-bromo-2-methylprop-1-ene and 3-bromobut-1-ene with chlorosilanes also proceed smoothly to give regioselectively allylic rearrangement products in good yields. Mediated by indium, dichlorosilanes (R2SiCl2) and trichlorosilanes (RSiCl3) can either afford monoallylated silanes or diallylated silanes depending on the amount of allyl bromide and indium used.

Controlled introduction of allylic group to chlorosilanes

Allylation of chlorosilanes has been achieved with allylsamarium bromide, especially in a controlled manner. Thus allylation of trisubstituted chlorosilanes (R3SiCl) afforded a variety of aryl, aralkyl, and alkenyl substituted allylsilanes. Dichlorosilanes (R2SiCl2) can either afford monoallylated silanes or diallylated silanes depending on the amount of allylsamarium bromide used. Similarly, trichlorosilanes (RSiCl3) can selectively afford mono-, di-, and tri-allylation products. Finally, perchlorosilane (SiCl4) was allylated stepwise and the corresponding silanes containing one, two, three or four allylic groups, respectively, were obtained in satisfactory yields.