263359-79-1

Basic information

• Product Name: (1R,5S,8S)-8-{(E)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-but-1-enyl}-1-(4,4-dimethoxy-1-methylene-butyl)-2,4-dioxa-bicyclo[3.2.1]octan-3-one
• CAS NO: 263359-79-1
• Molecular Weight: 606.875
• Mol File: 263359-79-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,5S,8S)-8-{(E)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-but-1-enyl}-1-(4,4-dimethoxy-1-methylene-butyl)-2,4-dioxa-bicyclo[3.2.1]octan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,5S,8S)-8-{(E)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-but-1-enyl}-1-(4,4-dimethoxy-1-methylene-butyl)-2,4-dioxa-bicyclo[3.2.1]octan-3-one(263359-79-1)
• EPA Substance Registry System: (1R,5S,8S)-8-{(E)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-but-1-enyl}-1-(4,4-dimethoxy-1-methylene-butyl)-2,4-dioxa-bicyclo[3.2.1]octan-3-one(263359-79-1)

Safety Data

• Hazardous Substances Data: 263359-79-1(Hazardous Substances Data)

Upstream product

• 32315-10-9 bis(trichloromethyl) carbonate 

Downstream Products

• 263359-82-6 5-[1-[(1R,5S,8S)-1-(4,4-Dimethoxy-1-methylene-butyl)-3-oxo-2,4-dioxa-bicyclo[3.2.1]oct-8-yl]-meth-(E)-ylidene]-2-(diphenoxy-phosphoryl)-6-methyl-heptanoic acid methyl ester 
• 1027055-66-8 2-(Diphenoxy-phosphoryl)-6-methyl-5-[1-[(1R,5S,8S)-1-(1-methylene-4-oxo-butyl)-3-oxo-2,4-dioxa-bicyclo[3.2.1]oct-8-yl]-meth-(E)-ylidene]-heptanoic acid methyl ester 

Relevant articles and documents

Total synthesis of 6-epi-sarsolilide A

This paper describes an asymmetric synthesis of 6-epi-sarsolilide A. The 11-membered carbocycle and seven-membered lactone were established by an intramolecular HWE reaction and iodolactonization. (C) 2000 Elsevier Science Ltd.