263387-46-8

Upstream product

• 204916-61-0 1-(tert-butyl-diphenyl-silanyloxy)-but-3-en-2-one 
• 263387-43-5 [(1R,2R,4aS,8aS)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2,4a-trimethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl]-acetaldehyde 
• 26742-33-6 (4aS)-1,4aβ-dimethyl-4,4a,7,8-tetrahydronaphthalene-2,5(3H,6H)-dione-5-ethyeneacetal 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 263387-42-4 [(1R,2R,4aS,8aS)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2,4a-trimethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl]-acetic acid ethyl ester 
• 263387-40-2 ((1R,2R,4aS,8aS)-1,2,4a-Trimethyl-5-trifluoromethanesulfonyloxy-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl)-acetic acid ethyl ester 
• 263387-37-7 C₁₉H₃₀O₄ 
• 263387-38-8 C₁₉H₃₂O₄ 
• 263387-39-9 ((1R,2R,4aS,8aS)-1,2,4a-Trimethyl-5-oxo-decahydro-naphthalen-1-yl)-acetic acid ethyl ester 
• 263387-41-3 ((1R,2R,4aS,8aS)-5-Formyl-1,2,4a-trimethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl)-acetic acid ethyl ester 
• 218453-54-4 C₁₈H₂₈O₅ 
• 154698-93-8 2-((tertbutyldiphenylsilyl)oxy)-N-methoxy-N-methylacetamide 

Downstream Products

• 263387-47-9 Formic acid (R)-1-{(S)-2-[2-(tert-butyl-diphenyl-silanyloxy)-acetyl]-oxiranyl}-2-[(1R,2R,4aS,8aS)-5-(tert-butyl-diphenyl-silanyloxymethyl)-1,2,4a-trimethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl]-ethyl ester 

Relevant academic research and scientific papers

Total synthesis of 15-deoxoclerocidin

Enantiomerically pure 15-deoxoclerocidin (14), 15-dihydro-12-O- formylclerocidin (19) and 12-O-formyl-15,20-tetrahydroclerocidin (18) were synthesized from a methyl-substituted Wieland Miescher ketone (3). (C) 2000 Elsevier Science Ltd.