263900-61-4

Basic information

• Product Name: 1,3-bis[2-(chloromethylphenoxy)methyl]benzene
• Synonyms: 1,3-bis[2-(chloromethylphenoxy)methyl]benzene
• CAS NO: 263900-61-4
• Molecular Weight: 387.306
• Mol File: 263900-61-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3-bis[2-(chloromethylphenoxy)methyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-bis[2-(chloromethylphenoxy)methyl]benzene(263900-61-4)
• EPA Substance Registry System: 1,3-bis[2-(chloromethylphenoxy)methyl]benzene(263900-61-4)

Safety Data

• Hazardous Substances Data: 263900-61-4(Hazardous Substances Data)

Upstream product

• 90-02-8 salicylaldehyde 
• 626-15-3 1,3-bis-(bromomethyl)benzene 
• 263900-71-6 1,3-bis[2-(hydroxymethylphenoxy)methyl]benzene 
• 140160-96-9 2,2'-(1,3-phenylenebis(methylene))bis(oxy)dibenzaldehyde 

Downstream Products

• 1131647-12-5 C₃₂H₃₃NO₂S₂ 

Relevant articles and documents

Coordination behaviors of a 23-membered NO4S2-macrocycle: Mononuclear silver(I) complex and conformational isomers of tetranuclear bis(macrocycle) mercury(II) complexes exhibiting exo- and endo/exocyclic coordination modes

A ditopic 23-membered NO4S2-macrocycle (L) incorporating both semi-rigid and flexible binding sites was synthesized and its silver(I) and mercury(II) complexes exhibiting different stoichiometries and coordination modes were prepared. First, silver(I) perchlorate reacts with L to afford an endocyclic mononuclear complex [Ag(L)]ClO4 (1) in which the silver(I) ion locates at the semi-rigid binding site in the cavity. The solution study for the silver(I) complexation via the 1H NMR titration agrees with the corresponding solid state data that show the endo-mode. Interestingly, the reaction of L with HgI2 led to the isolation of two conformational isomers with a tetranuclear bis(macrocycle) composition, [(exoHgLI2)2(μ-Hg2I4)] (2a) and [(endoHgLI2)2(μ-Hg2I4)] (2b), which are dominated by the coordination modes of L toward the mercury(II) center. In both conformers, two exocyclic mercury(II) complex units (exoHgLI2)2 in 2a or two endocyclic complex units [(endoHgLI2)2 in 2b are linked by tetraiododimercury(II) core (μ-Hg2I4) to give a 4:2 (metal-to-ligand) stoichiometry. Based on the packing structures and high temperature experiment, the intermolecular interactions might be responsible for the formation of 2a and 2b which are kinetically and thermodynamic controlled, respectively.

Thiaoxaaza-macrocyclic chromoionophores as mercury(II) sensors: Synthesis and color modulation

Azo-coupled macrocyclic chromoionophores incorporating benzene (L 1) and pyridine (L2) subunits were synthesized, respectively. In a cation-induced color change experiment, both receptors showed Hg2+ selectivity. However,