26397-37-5Relevant articles and documents
Reactions of the cumyloxyl and benzyloxyl radicals with strong hydrogen bond acceptors. Large enhancements in hydrogen abstraction reactivity determined by substrate/radical hydrogen bonding
Salamone, Michela,Dilabio, Gino A.,Bietti, Massimo
, p. 10479 - 10487 (2013/02/22)
A kinetic study on hydrogen abstraction from strong hydrogen bond acceptors such as DMSO, HMPA, and tributylphosphine oxide (TBPO) by the cumyloxyl (CumO?) and benzyloxyl (BnO?) radicals was carried out in acetonitrile. The reactions
Diffusion controlled hydrogen atom abstraction from tertiary amines by the benzyloxyl radical. the importance of C-H/N hydrogen bonding
Salamone, Michela,Anastasi, Gloria,Bietti, Massimo,Dilabio, Gino A.
supporting information; experimental part, p. 260 - 263 (2011/03/22)
The rate constants for H-atom abstraction (kH) from 1,4-cyclohexadiene (CHD), triethylamine (TEA), triisobutylamine (TIBA), and DABCO by the cumyloxyl (CumO?) and benzyloxyl (BnO ?) radicals were measured. Comparable ksub
Determination of the Enthalpies of Formation of C6H5CH2O·, p-CH3OC6H4CH2O·, and C6H5CHOH Radicals by Photoionization Mass Spectrometry
Ponomarev,Takhistov,Orlov
, p. 1774 - 1776 (2007/10/03)
The enthalpies of formation (kJ mol-1) of PhCH2O· (125), p-CH3OC6H4CH2O· (-37), and PhCHOH radicals (28) were determined from the energies of appearance of the corresponding fragment ions. The reliability of these data is confirmed by the coincidence of the experimental results with those calculated by the method of isodesmic reactions.