264150-99-4Relevant academic research and scientific papers
Stereoselective synthesis of (Z)-1,2-dithio-1-alkenes via copper-catalyzed thiolation of (Z)-2-bromovinyl sulfides
Xu, Hui,Chen, Wanzhi,Chen, Jiuxi,Wu, Huayue
, p. 380 - 388 (2012/03/26)
We describe a new method for the stereoselective synthesis of (Z)-1,2-dithio-1-alkenes via copper-catalyzed cross-coupling of (Z)-2-bromovinyl sulfides and thiols. The desired products are obtained in good to excellent yields. The double bond geometry of the starting (Z)-2-bromovinyl sulfides is retained under these reaction conditions. Georg Thieme Verlag Stuttgart New York.
