264609-10-1Relevant academic research and scientific papers
Synthesis, Crystal Structure, and Application of the Oxonium Acid [H(OEt2)2]+[B(C6F5) 4]-
Jutzi, Peter,Müller, Christian,Stammler, Anja,Stammler, Hans-Georg
, p. 1442 - 1444 (2000)
The reaction of LiB(C6F5)4 with HCl in diethyl ether afforded the new oxonium acid [H(OEt2)2]+-[B(C6F5) 4]- (1) as a colorless crystalline solid, which was characterized by NMR spectroscopy, by elemental analysis, and by single-crystal X-ray diffraction. The application of 1 is demonstrated in the generation of the complex {[η5-C5H3(CH2CH 2NMe2)CMe2-η5-C 13H8]ZrCH3}+-[B(C6F 5)4]- (3), containing an intramolecularly donorstabilized alkylzirconocene cation.
