26482-47-3Relevant academic research and scientific papers
Selective selenocatalytic allylic chlorination
Tunge, Jon A.,Mellegaard, Shelli R.
, p. 1205 - 1207 (2007/10/03)
Ene-chlorination of olefins by N-chlorosuccinimide is catalyzed by phenylselenenyl chloride. This reaction demonstrates the catalytic conversion of C-H bonds into more reactive C-Cl bonds.
Studies on the Autoxidation of Branched-chain Olefins. I. Autoxidation of 2-Methylalk-1-enes and 2-Methylalk-2-enes
Bilas, W.,Hoebold, W.,Pritzkow, W.
, p. 125 - 141 (2007/10/02)
The products of the autoxidation of 2-methylpent-1-ene, 2-methylpent-2-ene, 2-methylhex-1-ene, 2-methylhex-2-ene, 2,4,4-trimethylpent-1-ene, and 2,4,4-trimethylpent-2-ene were analyzed by gas chromatography.The identification of the products corresponding to the individual peaks was possible by comparison with authentic substances or by preparative gaschromatographic separation and n.m.r.-spectroscopy of the isolated samples.In this way not only the epoxides and the products of the oxidative cleavage of the C=C double bond but also the allylic alcohols formed by LiAlH4-reduction of the oxidation mixtures could be identified and analyzed.From the results the compositions of the original oxidation mixtures were calculated.
