264872-39-1

Basic information

• Product Name: 5-O-benzyl-2-[(tert-butoxycarbonyl)(methyl)amino]-1,2,4-trideoxy-3-O-(methoxymethyl)-1-phenyl-D-threo-pentitol
• Synonyms: 5-O-benzyl-2-[(tert-butoxycarbonyl)(methyl)amino]-1,2,4-trideoxy-3-O-(methoxymethyl)-1-phenyl-D-threo-pentitol
• CAS NO: 264872-39-1
• Molecular Weight: 443.583
• Mol File: 264872-39-1.mol

Chemical Properties

• CAS DataBase Reference: 5-O-benzyl-2-[(tert-butoxycarbonyl)(methyl)amino]-1,2,4-trideoxy-3-O-(methoxymethyl)-1-phenyl-D-threo-pentitol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-O-benzyl-2-[(tert-butoxycarbonyl)(methyl)amino]-1,2,4-trideoxy-3-O-(methoxymethyl)-1-phenyl-D-threo-pentitol(264872-39-1)
• EPA Substance Registry System: 5-O-benzyl-2-[(tert-butoxycarbonyl)(methyl)amino]-1,2,4-trideoxy-3-O-(methoxymethyl)-1-phenyl-D-threo-pentitol(264872-39-1)

Safety Data

• Hazardous Substances Data: 264872-39-1(Hazardous Substances Data)

Upstream product

• 264872-37-9 2-amino-5-O-benzyl-1,2,4-trideoxy-3-O-(methoxymethyl)-1-phenyl-D-threo-pentitol 
• 264872-36-8 5-O-benzyl-1,4-dideoxy-3-O-(methoxymethyl)-1-phenyl-D-threo-pentitol 
• 264872-43-7 C₂₀H₂₄O₃ 
• 264872-33-5 5-O-benzyl-1-chloro-1,4-dideoxy-D-threo-pentitol 
• 264872-35-7 4,5-anhydro-1-O-benzyl-2-deoxy-3-O-(methoxymethyl)-D-threo-pentitol 
• 264872-34-6 4,5-anhydro-1-O-benzyl-2-deoxy-D-threo-pentitol 
• 264872-32-4 (E)-(((5-chloropent-3-en-1-yl)oxy)methyl)benzene 
• 89923-31-9 (E)-5-(benzyloxy)pent-2-en-1-ol 
• 24424-99-5 di-tert-butyl dicarbonate 
• 264872-38-0 5-O-benzyl-2-[(tert-butoxycarbonyl)amino]-1,2,4-trideoxy-3-O-(methoxymethyl)-1-phenyl-D-threo-pentitol 
• 74-88-4 methyl iodide 

Downstream Products

• 229981-04-8 (3R,4S)-4--3-(methoxymethoxy)-5-phenylpentanoic acid 
• 229981-25-3 (3R,4S)-4--3-(methoxymethoxy)-1-hydroxy-5-phenylpentane 

Relevant articles and documents

Synthesis of the γ-amino-β-hydroxy acid of hapalosin via an asymmetric dihydroxylation route

Starting from the allylic alcohol 3, the epoxide 7 was prepared by asymmetric dihydroxylation of the allylic chloride followed by subsequent protection of the secondary hydroxy group. Opening of the oxirane with phenyl cuprate gave the triol 8 with a free hydroxy group. Mitsunobu reaction of 8 with diphenylphosphoryl azide led to the azide 9. Simple functional group manipulations delivered the acid 2 in further five steps. (C) 2000 Elsevier Science Ltd.