264889-07-8

Basic information

• Product Name: [Pd(η3-1,1',3,3'-tetramethylpropadiene)(6-Me-C5H3N-2-CH2S(Ph))]ClO4
• CAS NO: 264889-07-8
• Molecular Weight: 532.397
• Mol File: 264889-07-8.mol

Chemical Properties

• CAS DataBase Reference: [Pd(η3-1,1',3,3'-tetramethylpropadiene)(6-Me-C5H3N-2-CH2S(Ph))]ClO4(CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(η3-1,1',3,3'-tetramethylpropadiene)(6-Me-C5H3N-2-CH2S(Ph))]ClO4(264889-07-8)
• EPA Substance Registry System: [Pd(η3-1,1',3,3'-tetramethylpropadiene)(6-Me-C5H3N-2-CH2S(Ph))]ClO4(264889-07-8)

Safety Data

• Hazardous Substances Data: 264889-07-8(Hazardous Substances Data)

Upstream product

• 1000-87-9 2,4-dimethyl-2,3-pentadiene 
• 264888-95-1 [PdCl(Me)(6-Me-C₅H₃N-2-CH₂S(Ph))] 
• 63936-85-6 [PdCl(Me)(1,5-cyclodiene)] 

Relevant articles and documents

Remarkable, sterically induced rate enhancement in the insertion of allenes into palladium-methyl bonds

The rate of insertion of methyl-substituted allenes into the Pd-Me bond in chelate pyridine-thioether complexes [PdCl(Me)(R′N-SR)] (R′N-SR = 6-R′-C5H3N-2-CH2SR) to give 2-methylallyl derivatives is remarkably enhanced by t