264889-41-0

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 264889-39-6 [(2S)-4-((4S)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-hydroxybutyl]-4-methylbenzenesulfonate 
• 492463-94-2 Toluene-4-sulfonic acid (2S,5S)-2,5,6-trihydroxy-hexyl ester 
• 24211-51-6 (2S,5S)-hexane-1,2,5,6-tetrol 
• 3427-24-5 (2S,3E,5S)-1,2,5,6-tetrahydroxy-1,2:5,6-di-O-isopropylidene-hex-3-ene 

Downstream Products

• 264889-48-7 (E)-(3R,6S,9R)-9-(tert-Butyl-diphenyl-silanyloxy)-1-((S)-4-isopropyl-2-thioxo-thiazolidin-3-yl)-3,6-bis-methoxymethoxy-dec-4-en-1-one 
• 264889-47-6 (E)-(3R,6S,9R)-9-(tert-Butyl-diphenyl-silanyloxy)-3-hydroxy-1-((S)-4-isopropyl-2-thioxo-thiazolidin-3-yl)-6-methoxymethoxy-dec-4-en-1-one 
• 264889-49-8 (E)-(3R,6S,9R)-9-(tert-Butyl-diphenyl-silanyloxy)-3,6-bis-methoxymethoxy-dec-4-enoic acid 
• 264889-43-2 2,2-Dimethyl-propionic acid (2S,5R)-5-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-hexyl ester 
• 264889-46-5 (E)-(4S,7R)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methoxymethoxy-oct-2-enal 
• 264889-44-3 (2S,5R)-5-(tert-Butyl-diphenyl-silanyloxy)-2-methoxymethoxy-hexan-1-ol 
• 140460-53-3 (-)-decarestrictine C₂ 
• 264889-42-1 (2S,5R)-5-(tert-Butyl-diphenyl-silanyloxy)-hexane-1,2-diol 

Relevant academic research and scientific papers

Total synthesis of (-)-(3R,6S,9R)-decarestrictine C2

Enantioselective synthesis of the proposed structure Of (-)-(3R,6S,9R)- decarestrictine C2 (4) has been accomplished using (2S,5S)-1,2,5,6- hexanetenterol (9) as a C2-symmetric chiral synthon, in which the diastereoselective aldol-type reaction of a tin(II) enolate of 3-acetyl-4(S)- isopropyl-1,3-thiazolidine-2-thione with the α,β-unsaturated aldehyde was used as a key step. (C) 2000 Elsevier Science Ltd.