264918-89-0

Upstream product

• 264918-92-5 [(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl]-methanol 
• 440334-00-9 tert-Butyl-dimethyl-((2R,4aR,6S,7R,9aS)-2-phenyl-6-vinyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-yloxy)-silane 
• 213815-32-8 (2R,4aR,6S,7R,9aS)-2-Phenyl-6-vinyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 264918-94-7 (4aS,6R,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-octahydro-1,5-dioxa-benzocycloocten-7-one 
• 264918-97-0 (4aS,6R,9S,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-9-methyl-octahydro-1,5-dioxa-benzocycloocten-7-one 

Relevant academic research and scientific papers

Convergent synthesis of an HIJK ring model of ciguatoxin via Suzuki cross-coupling reaction

Convergent synthesis of HIJK ring model compound 1 of ciguatoxin is described. The present synthesis relied on a palladium-catalyzed Suzuki cross-coupling reaction between eight-membered ketene acetal phosphate 2 and seven-membered alkylborane 6. (C) 2000