264920-94-7

Basic information

• Product Name: (E)-(2S,3R)-7-(4-Methoxy-benzyloxy)-2,4-dimethyl-3-triethylsilanyloxy-hept-4-enoic acid methyl ester
• Synonyms: (E)-(2S,3R)-7-(4-Methoxy-benzyloxy)-2,4-dimethyl-3-triethylsilanyloxy-hept-4-enoic acid methyl ester
• CAS NO: 264920-94-7
• Molecular Weight: 436.664
• Mol File: 264920-94-7.mol

Chemical Properties

• CAS DataBase Reference: (E)-(2S,3R)-7-(4-Methoxy-benzyloxy)-2,4-dimethyl-3-triethylsilanyloxy-hept-4-enoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(2S,3R)-7-(4-Methoxy-benzyloxy)-2,4-dimethyl-3-triethylsilanyloxy-hept-4-enoic acid methyl ester(264920-94-7)
• EPA Substance Registry System: (E)-(2S,3R)-7-(4-Methoxy-benzyloxy)-2,4-dimethyl-3-triethylsilanyloxy-hept-4-enoic acid methyl ester(264920-94-7)

Safety Data

• Hazardous Substances Data: 264920-94-7(Hazardous Substances Data)

Upstream product

• 264920-92-5 (4R,5S)-3-[(E)-(2S,3R)-3-Hydroxy-7-(4-methoxy-benzyloxy)-2,4-dimethyl-hept-4-enoyl]-4-methyl-5-phenyl-oxazolidin-2-one 
• 110597-90-5 (E)-5-(4-methoxyphenylmethyloxy)-2-methyl-2-pentenal 
• 79271-56-0 triethylsilyl trifluoromethyl sulfonate 
• 264920-93-6 (E)-(2S,3R)-3-Hydroxy-7-(4-methoxy-benzyloxy)-2,4-dimethyl-hept-4-enoic acid methyl ester 

Downstream Products

• 264920-96-9 Triethyl-[(E)-(R)-5-(4-methoxy-benzyloxy)-1-((E)-(R)-3-methoxy-1-methyl-allyl)-2-methyl-pent-2-enyloxy]-silane 
• 264920-88-9 (E)-(2S,3R)-7-(4-Methoxy-benzyloxy)-2,4-dimethyl-3-triethylsilanyloxy-hept-4-enal 
• 264921-01-9 3-{(4R,5R)-5-[(E)-4-(4-Methoxy-benzyloxy)-1-methyl-but-1-enyl]-4-methyl-tetrahydro-furan-2-yl}-propan-1-ol 
• 264920-99-2 Acetic acid (4R,5R)-5-[(E)-4-(4-methoxy-benzyloxy)-1-methyl-but-1-enyl]-4-methyl-tetrahydro-furan-2-yl ester 
• 264921-00-8 (2R,3R)-5-Allyl-2-[(E)-4-(4-methoxy-benzyloxy)-1-methyl-but-1-enyl]-3-methyl-tetrahydro-furan 
• 264920-97-0 (2R,3R)-5-Methoxy-2-[(E)-4-(4-methoxy-benzyloxy)-1-methyl-but-1-enyl]-3-methyl-tetrahydro-furan 
• 264920-98-1 (4R,5R)-5-[(E)-4-(4-Methoxy-benzyloxy)-1-methyl-but-1-enyl]-4-methyl-tetrahydro-furan-2-ol 
• 264920-95-8 (E)-(2R,3R)-7-(4-Methoxy-benzyloxy)-2,4-dimethyl-3-triethylsilanyloxy-hept-4-en-1-ol 

Relevant articles and documents

Studies toward (-)-Gymnodimine: concise routes to the spirocyclic and tetrahydrofuran moieties

(formula presented) (-)-Gymnodimine is a member of a unique class of potent marine toxins possessing imines within a spirocylic array. Herein we report the synthesis of the tetrahydrofuran fragment and a strategy toward the spirocyclic imine fragment of this family of toxins. Key reactions include an asymmetric anti-aldol reaction to set the stereochemistry of the tetrahydrofuran and a formal, intermolecular Diels-Alder reaction involving an α-methylene-δ-lactam and a dienyne.