265114-80-5Relevant academic research and scientific papers
Synthesis of bis(phosphonatomethyl)-,bis(phosphinatomethyl)-, and bis(phosphinoxidomethyl)amines, as well as related ring bis(phosphine) platinum complexes
Keglevich, Gyoergy,Szekrenyi, Anna,Szoe llosy, Aron,Drahos, Laszlo
experimental part, p. 2265 - 2272 (2011/07/07)
The double Kabachnik-Fields condensation of primary amines with 2 equivalents of the other reagents (formaldehyde and a >P(O)H species, such as dialkyl phosphites, diphenylphosphine oxide, as well as the related dioxaphosphorine and oxaphosphorine derivatives) carried out under microwave conditions afforded the title products in 79-94% yields. The bis(phosphinoxidomethyl)amines were converted, after double deoxygenation, to the corresponding ring platinum complexes. Copyright
