26532-23-0

Basic information

• Product Name: (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL
• Synonyms: (z)-2-(3,3-dimethylcyclohexylidene)ethanol;-, Z;3-dimethylcyclohexylidene)-2-((z)-ethano;Ethanol, 2-(3,3-dimethylcyclohexylidene)-, (Z)-;Ethanol, 2-3,3-dimethylcyclohexylidene;(Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL;GRANDLURE II;GrandlureII,Z-Isomerof
• CAS NO: 26532-23-0
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.25
• Mol File: 26532-23-0.mol

Chemical Properties

• Boiling Point: 212.7±8.0℃ (760 Torr)
• Flash Point: 90.0±8.3℃
• Appearance: /
• Density: 0.966±0.06 g/cm3 (20 ºC 760 Torr)
• Refractive Index: 1.4771 (25℃)
• CAS DataBase Reference: (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL(26532-23-0)
• EPA Substance Registry System: (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL(26532-23-0)

Safety Data

• Hazardous Substances Data: 26532-23-0(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical and Agrochemical Industries:
(Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL is utilized as a key intermediate in the synthesis of various pharmaceuticals and agrochemicals, contributing to the development of new drugs and agricultural products.
Used in Fragrance Industry:
In the personal care and household products sector, (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL serves as a fragrance ingredient, enhancing the scent profiles of different consumer goods.
Used as a Chemical Intermediate:
(Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL also has potential applications as a chemical intermediate in the production of other organic compounds, expanding its utility across various chemical industries.

InChI:InChI=1/C10H18O/c1-8(11)9-5-4-6-10(2,3)7-9/h11H,4-7H2,1-3H3/b9-8-

Upstream product

• 30346-23-7 3,3-Dimethyl-Z-cyclohexylidenessigsaeuremethylester 
• 82528-39-0 6-phenylthio-2-ochtoden-1-ol 
• 82528-53-8 (2Z)-1-hydroxy-2-ochtoden-6-one 
• 121617-98-9 (Z)-2-ochtoden-1-ol tetrahydropyranyl ether 
• 30346-27-1 (E)-2-(3,3-Dimethylcyclohexylidene)ethanol 
• 82528-42-5 (EZ)-1-hydroxy-2-ochtoden-6-one 
• 82528-42-5 (2E)-1-hydroxy-2-ochtoden-6-one 
• 4698-08-2 (E)-geranic acid 
• 55298-92-5 methyl 3-methylene-7-methyl-6-octenoate 
• 30346-22-6 3,3-Dimethyl-1-hydroxy-cyclohexylessigsaeure 
• 5629-80-1 (1-hydroxy-3,3-dimethyl-cyclohexyl)-acetic acid ethyl ester 
• 82528-41-4 (EZ)-6-oxo-2-ochtoden-1-yl trifluoroacetate 
• 121618-03-9 (E)-6-oxo-2-ochtoden-1-yl 3,5-dinitrobenzoate 
• 121617-96-7 (E)-2-ochtoden-1-ol tetrahydropyranyl ether 

Downstream Products

• 26532-24-1 (Z)-3,3-Dimethylcyclohexane-Δ^1,?-acetaldehyde 

Relevant articles and documents

THE STEREOSPECIFIC FORMATION OF AN EXOCYCLIC ALKENE BY A CONSECUTIVE RADICAL CYCLIZATION-ELEIMINATION

The iodovinylstannanes 4 and 5 were prepared by the conjugate addition of the tri-n-butyltin moiety to a substituted propiolic ester.Compounds 4 and 5 underwent a radical cyclization-elimination reaction to stereospecifically generate an exocyclic alkene.

Pheromone Synthesis, CXV. - Synthesis of (Z)-2-Ochtoden-1-ol, (E)-2-Ochtoden-1-al, and (Z)-2-Ochtoden-1-al, the Pheromone Components of the Boll Weevil (Anthonomus grandis)

The synthesis of geometrically pure (Z)-2-ochtoden-1-ol (1), (E)-2-ochtoden-1-al (2), and (Z)-2-ochtoden-1-al (3) was achieved starting from myrcene.

SYNTHETIC STUDIES ON THE OCHTODANE TYPE TERPENES I. STEREOSELECTIVE CONSTRUCTION OF THE OCHTODANE SKELETON FROM MYRCENE.

The ochtodane skeleton, the Carbon framework of 1,1-dimethyl-3-ethylcyclohexane (1) was constructed highly stereoselectively by the acid-catalyzed (SnCl//4 or CF//3CO//2H) cyclization of the terminally functionalized myrcene derivatives, the benzenesulfenyl chloride adduct (7), the terminal beta -hydroxy sulfide (8) derived from 7, and myrcene 6,7-epoxide (10). The stereoselectivity of the 3-exo-double bond in 1 formed concomitantly in the cyclization reaction was found to depend remarkably upon the reaction temperture and the 85-94% of E-stereoselectivity was attained at minus 78 degree C. By the method, the ochtodane derivatives with the sulfur- or oxygen-functional groups on the C(6)-position were obtained.