26533-33-5Relevant academic research and scientific papers
Salt effects on the reactivity and the stability of organomanganese reagents
Cahiez, Gerard,Razafintsalama, Lynah,Laboue, Blandine,Chau, Francois
, p. 849 - 852 (2007/10/03)
The reactivity and the stability of organomanganese reagents prepared from the ate complexes MnX2·2LiBr (X= Br,I) and MnCl2·R4NX (X= Br, Cl) were studied. The preparation and the use for synthetic applications of stable sec- and tert-alkylmanganese bromides in ether as well as the acylation of RMnCl by R'COOCOOEt in THF were successfully achieved for the first time.
The evaluation of dicyclopentadienylsamarium as a reagent in organic synthesis
Namy,Collin,Zhang,Kagan
, p. 81 - 86 (2007/10/02)
SmCp2, which is easily prepared from SmI2, has been screened as a reducing agent for organic chemistry. In particular, SmCp2 promotes the pseudo-Barbier reaction between carbonyl compounds (aldehydes and ketones) and aliphatic or allylic halides more efficiently than does SmI2.
ORGANOMANGANESE (II) REAGENTS XIII1: HIGHLY SELECTIVE ADDITION OF ORGANOMANGANESE HALIDES TO ALDEHYDES IN THE PRESENCE OF KETONES
Cahiez, G.,Figadere, B.
, p. 4445 - 4448 (2007/10/02)
Organomanganese halides add quite selectively to aldehydes in the presence of ketones to give the corresponding secondarry alcohols in excellent yields.
