26533-77-7

Basic information

• Product Name: (R)-4-<(E/Z)-5-hydroxy-3-methylpent-3-en-1-ynyl>-3,5,5-trimethylcyclohex-3-enol
• CAS NO: 26533-77-7
• Molecular Weight: 234.338
• Mol File: 26533-77-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-4-<(E/Z)-5-hydroxy-3-methylpent-3-en-1-ynyl>-3,5,5-trimethylcyclohex-3-enol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-<(E/Z)-5-hydroxy-3-methylpent-3-en-1-ynyl>-3,5,5-trimethylcyclohex-3-enol(26533-77-7)
• EPA Substance Registry System: (R)-4-<(E/Z)-5-hydroxy-3-methylpent-3-en-1-ynyl>-3,5,5-trimethylcyclohex-3-enol(26533-77-7)

Safety Data

• Hazardous Substances Data: 26533-77-7(Hazardous Substances Data)

Upstream product

• 152125-31-0 (4R,6R)-2,2,6-Trimethyl-4-trimethylsilanyloxy-cyclohexanone 
• 20548-02-1 (4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexan-1-one 
• 160332-74-1 2-cis-5-<(4'R)-4'-acetoxy-2',6',6'-trimethylcyclohex-1'-enyl>-3-methyl-2-penten-4-yn-1-yl acetate 
• 160332-73-0 (-)-(1'R,4'R,6'R)-(Z)-5-(1',4'-dihydroxy-2',2',6'-trimethylcyclohexyl)-3-methyl-2-penten-4-yn-1-ol 

Downstream Products

• 144-68-3 zeaxanthin 
• 70267-38-8 9-Z-(3R,3'R)-diatoxanthin 
• 160332-75-2 2-Z-5-((4'R)-4'-hydroxy-2',2',6'-trimethylcyclohex-1'-enyl)-3-methyl-2-penten-4-yn-1-al 

Relevant articles and documents

Total synthesis of acetylenic carotenoids. 3. First total synthesis of optically active 9-Z-(3R,3'R)-diatoxanthin and 9-Z-(3R)-7,8-didehydrocryptoxanthin.

Optically active 9-Z-(3R,3'R)-diatoxanthin and 9-Z-(3R)-7,8-didehydrocryptoxanthin were synthesised in an overall yield of 9percent and 11percent respectively, with a seven step C9+C6+C25=C40 strategy.A key intermediate was the previously undescribed C15-