2655-25-6Relevant academic research and scientific papers
Reinvestigation of the Electronic Spectrum of the Phenylnitrene Radical
Cullin, David W.,Yu, Lian,Williamson, James M.,Platz, Matthew S.,Miller, Terry A.
, p. 3387 - 3391 (1990)
The origin band of the electronic transition long attributed to gaseous triplet phenylnitrene has been investigated by using a very high resolution pulsed laser to interrogate molecules cooled in a supersonic jet.The observed rotational and spin structure
Photochemistry of Phenyl Azide: The Role of Singlet and Triplet Phenylnitrene as Transient Intermediates
Leyva, Elisa,Platz, Matthew S.,Persy, Gabriele,Wirz, Jakob
, p. 3783 - 3790 (2007/10/02)
The sequence of transient intermediates formed by the photolysis of phenyl azide (1) was determined by a combination of techniques including absorption, emission, and EPR spectroscopies as well as quantitative product analyses of irradiated glassy solutio
Reactions of CHF (1A') and NCO (2Π) Radicals
Cookson, J. L.,Hancock, G.,McKendrick, K. G.
, p. 335 - 336 (2007/10/02)
Infrared multiple photon dissociation has been used to produce ground state radicals CHF(1A') and NCO(2Π), and their kinetic behaviour in the presence of added gases studied by time resolved laser induced fluorescence.Both kinetics and the products of reactions of CHF with NO, NO2, O and N atoms, and of NCO with NO will be discussed. - Keywords: Chemical Kinetics / Multi-photon Processes / Photochemistry / Radicals
